Kinetics and Catalysis

, том 55 , издание 6 , страницы 712-721

Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite

Тип публикации: Journal Article

Дата публикации: 2014-11-01

Pleiades Publishing

Kinetics and Catalysis

SCImago Q3

WOS Q4

БС2

SJR: 0.233

CiteScore: 2.1

Impact factor: 1

ISSN: 00231584, 16083210

DOI: 10.1134/s0023158414060135

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

Краткое описание

A mechanism is suggested for the heterogeneous catalytic epoxidation of allyl chloride with hydrogen peroxide in methanol. The kinetics of allyl chloride oxidation into epichlorohydrin in the presence of extruded titanium silicalite has been investigated. A kinetic model of the process has been derived from experimental data, and the activation energies of the target and side reactions, the rate constants of the reactions, and the adsorption equilibrium constant have been determined. The allyl chloride epoxidation process has been tested using a bench-scale continuous apparatus, and the adequacy of the kinetic model has been estimated.

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Метрики

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ГОСТ |

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Sulimov A. V. et al. Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite // Kinetics and Catalysis. 2014. Vol. 55. No. 6. pp. 712-721.

ГОСТ со всеми авторами (до 50) Скопировать

Sulimov A. V., Danov S. M., Ovcharova A. V., Ovcharov A. A., Flid V. R. Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite // Kinetics and Catalysis. 2014. Vol. 55. No. 6. pp. 712-721.

RIS |

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RIS Скопировать

TY - JOUR

DO - 10.1134/s0023158414060135

UR - https://doi.org/10.1134/s0023158414060135

TI - Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite

T2 - Kinetics and Catalysis

AU - Sulimov, A V

AU - Danov, S M

AU - Ovcharova, A V

AU - Ovcharov, A A

AU - Flid, V R

PY - 2014

DA - 2014/11/01

PB - Pleiades Publishing

SP - 712-721

IS - 6

VL - 55

SN - 0023-1584

SN - 1608-3210

ER -

BibTex |

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@article{2014_Sulimov,

author = {A V Sulimov and S M Danov and A V Ovcharova and A A Ovcharov and V R Flid},

title = {Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite},

journal = {Kinetics and Catalysis},

year = {2014},

volume = {55},

publisher = {Pleiades Publishing},

month = {nov},

url = {https://doi.org/10.1134/s0023158414060135},

number = {6},

pages = {712--721},

doi = {10.1134/s0023158414060135}

}

MLA

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MLA Скопировать

Sulimov, A. V., et al. “Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite.” Kinetics and Catalysis, vol. 55, no. 6, Nov. 2014, pp. 712-721. https://doi.org/10.1134/s0023158414060135.

Издатель

Pleiades Publishing

Журнал

Kinetics and Catalysis

SCImago Q3

WOS Q4

БС2

SJR

0.233

CiteScore

2.1

Impact factor

ISSN

00231584 (Print)

16083210 (Electronic)

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