Kinetics and Catalysis, volume 57, issue 6, pages 821-825
Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide
Publication type: Journal Article
Publication date: 2016-11-01
Journal:
Kinetics and Catalysis
Q3
Q4
SJR: 0.254
CiteScore: 2.1
Impact factor: 1.3
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The reaction of carbon dioxide with propylene oxide in the presence of the (salen)CoCl or (TPP)CoCl (salen = bis(3,5-di-tert-butyl-salicylidene)-1,2-diaminocyclohexane, TPP = 5,10,15,20-tetraphenylporphyrin) catalyst and the PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst has been carried out at 20–60°С and a СО2 pressure of 0.6 MPa to investigate the effect of the ligand nature on the reaction rate and selectivity. The change in the reaction rate and selectivity in relation to the temperature and cocatalyst/catalyst ratio has been studied. The activation energy of the copolymerization of СО2 with propylene oxide catalyzed by the (salen)CoCl complex have been obtained.
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Chukanova O. M., Belov G. P. Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide // Kinetics and Catalysis. 2016. Vol. 57. No. 6. pp. 821-825.
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Chukanova O. M., Belov G. P. Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide // Kinetics and Catalysis. 2016. Vol. 57. No. 6. pp. 821-825.
Cite this
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TY - JOUR
DO - 10.1134/s0023158416050074
UR - https://doi.org/10.1134/s0023158416050074
TI - Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide
T2 - Kinetics and Catalysis
AU - Chukanova, O M
AU - Belov, G P
PY - 2016
DA - 2016/11/01
PB - Pleiades Publishing
SP - 821-825
IS - 6
VL - 57
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Chukanova,
author = {O M Chukanova and G P Belov},
title = {Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide},
journal = {Kinetics and Catalysis},
year = {2016},
volume = {57},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/s0023158416050074},
number = {6},
pages = {821--825},
doi = {10.1134/s0023158416050074}
}
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MLA
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Chukanova, O. M., and G P Belov. “Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide.” Kinetics and Catalysis, vol. 57, no. 6, Nov. 2016, pp. 821-825. https://doi.org/10.1134/s0023158416050074.