Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation
D V Glyzdova
1, 2
,
N S Smirnova
1
,
N N Leonteva
2
,
E. Yu. Gerasimov
3
,
I P Prosvirin
3
,
V I Vershinin
2
,
D.A Shlyapin
1
,
P.G Tsyrulnikov
1
Publication type: Journal Article
Publication date: 2017-03-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
Pd/Sibunit and Pd–M/Sibunit (M = Ga, Zn, or Ag) catalysts have been synthesized, and their catalytic properties in liquid-phase acetylene hydrogenation have been investigated. Doping of the palladium catalyst with a metal M leads to the formation of the Pd2Ga, PdZn, or Pd0.46Ag0.54 bimetallic compound. The bimetallic particles are much smaller (1.6–2.0 nm) than the monometallic palladium particles (4.0 nm). Doping with zinc raises the ethylene selectivity by 25% without affecting the activity of the catalyst. Specific features of the effect of each of the dopants on palladium are reported.
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Total citations:
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Citations from 2024:
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GOST
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Glyzdova D. V. et al. Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation // Kinetics and Catalysis. 2017. Vol. 58. No. 2. pp. 140-146.
GOST all authors (up to 50)
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Glyzdova D. V., Smirnova N. S., Leonteva N. N., Gerasimov E. Y., Prosvirin I. P., Vershinin V. I., Shlyapin D., Tsyrulnikov P. Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation // Kinetics and Catalysis. 2017. Vol. 58. No. 2. pp. 140-146.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S0023158417020057
UR - https://doi.org/10.1134/S0023158417020057
TI - Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation
T2 - Kinetics and Catalysis
AU - Glyzdova, D V
AU - Smirnova, N S
AU - Leonteva, N N
AU - Gerasimov, E. Yu.
AU - Prosvirin, I P
AU - Vershinin, V I
AU - Shlyapin, D.A
AU - Tsyrulnikov, P.G
PY - 2017
DA - 2017/03/01
PB - Pleiades Publishing
SP - 140-146
IS - 2
VL - 58
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Glyzdova,
author = {D V Glyzdova and N S Smirnova and N N Leonteva and E. Yu. Gerasimov and I P Prosvirin and V I Vershinin and D.A Shlyapin and P.G Tsyrulnikov},
title = {Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation},
journal = {Kinetics and Catalysis},
year = {2017},
volume = {58},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S0023158417020057},
number = {2},
pages = {140--146},
doi = {10.1134/S0023158417020057}
}
Cite this
MLA
Copy
Glyzdova, D. V., et al. “Synthesis and characterization of Sibunit-supported Pd–Ga, Pd–Zn, and Pd–Ag catalysts for liquid-phase acetylene hydrogenation.” Kinetics and Catalysis, vol. 58, no. 2, Mar. 2017, pp. 140-146. https://doi.org/10.1134/S0023158417020057.