Kinetics and Catalysis, volume 58, issue 4, pages 397-401
Reaction between carbon dioxide and propylene oxide catalyzed by cobalt and chromium porphyrin complexes: The effect of reaction conditions on the reaction rate
Publication type: Journal Article
Publication date: 2017-07-01
Journal:
Kinetics and Catalysis
Q3
Q4
SJR: 0.254
CiteScore: 2.1
Impact factor: 1.3
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The effect of the conditions (time, temperature, pressure, and cocatalyst/catalyst ratio) on the rate and selectivity of the reaction between СО2 and propylene oxide catalyzed by TPPCrCl and TPPCoCl (TPP is 5,10,15,20-tetraphenylporphyrin) has been studied. The time variation of the reaction rate has been analyzed by measuring the СО2 uptake during the reaction. The observed dependences of the reaction rate on the temperature and cocatalyst/catalyst ratio are similar for TPPCrCl and TPPCoCl. In the presence of TPPCoCl, the reaction yields a mixture of poly(propylene carbonate) and a cyclic carbonate, while when TPPCrCl is used, only the cyclic carbonate is synthesized.
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Chukanova O. M., Belov G. P. Reaction between carbon dioxide and propylene oxide catalyzed by cobalt and chromium porphyrin complexes: The effect of reaction conditions on the reaction rate // Kinetics and Catalysis. 2017. Vol. 58. No. 4. pp. 397-401.
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Chukanova O. M., Belov G. P. Reaction between carbon dioxide and propylene oxide catalyzed by cobalt and chromium porphyrin complexes: The effect of reaction conditions on the reaction rate // Kinetics and Catalysis. 2017. Vol. 58. No. 4. pp. 397-401.
Cite this
RIS
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TY - JOUR
DO - 10.1134/s0023158417040048
UR - https://doi.org/10.1134/s0023158417040048
TI - Reaction between carbon dioxide and propylene oxide catalyzed by cobalt and chromium porphyrin complexes: The effect of reaction conditions on the reaction rate
T2 - Kinetics and Catalysis
AU - Chukanova, O M
AU - Belov, G P
PY - 2017
DA - 2017/07/01
PB - Pleiades Publishing
SP - 397-401
IS - 4
VL - 58
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Chukanova,
author = {O M Chukanova and G P Belov},
title = {Reaction between carbon dioxide and propylene oxide catalyzed by cobalt and chromium porphyrin complexes: The effect of reaction conditions on the reaction rate},
journal = {Kinetics and Catalysis},
year = {2017},
volume = {58},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/s0023158417040048},
number = {4},
pages = {397--401},
doi = {10.1134/s0023158417040048}
}
Cite this
MLA
Copy
Chukanova, O. M., and G P Belov. “Reaction between carbon dioxide and propylene oxide catalyzed by cobalt and chromium porphyrin complexes: The effect of reaction conditions on the reaction rate.” Kinetics and Catalysis, vol. 58, no. 4, Jul. 2017, pp. 397-401. https://doi.org/10.1134/s0023158417040048.