Role of Water in the Catalysis of Ethylene Di- and Oligomerization and Toluene Alkylation Reactions Based on Nickel Bis(Acetylacetonate) Systems
Тип публикации: Journal Article
Дата публикации: 2017-11-01
scimago Q3
wos Q4
БС2
SJR: 0.26
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Краткое описание
It is established that the turnover frequency and number of Ni(acac)2–50Et2AlCl or Ni(acac)2–50Et2AlCl · EtAlCl2-based systems in ethylene oligomerization processes depend on the concentration of the water in toluene. The possibility of the alkylation of toluene, used as a solvent under the considered reaction condition, is shown. The main reactions describing the role of water at the stage of the formation and functioning of catalytically active hydride nickel complexes are proposed.
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Titova Yu. Yu., Shmidt F. Role of Water in the Catalysis of Ethylene Di- and Oligomerization and Toluene Alkylation Reactions Based on Nickel Bis(Acetylacetonate) Systems // Kinetics and Catalysis. 2017. Vol. 58. No. 6. pp. 749-757.
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Titova Yu. Yu., Shmidt F. Role of Water in the Catalysis of Ethylene Di- and Oligomerization and Toluene Alkylation Reactions Based on Nickel Bis(Acetylacetonate) Systems // Kinetics and Catalysis. 2017. Vol. 58. No. 6. pp. 749-757.
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TY - JOUR
DO - 10.1134/s0023158417050214
UR - https://doi.org/10.1134/s0023158417050214
TI - Role of Water in the Catalysis of Ethylene Di- and Oligomerization and Toluene Alkylation Reactions Based on Nickel Bis(Acetylacetonate) Systems
T2 - Kinetics and Catalysis
AU - Titova, Yu Yu
AU - Shmidt, F.K
PY - 2017
DA - 2017/11/01
PB - Pleiades Publishing
SP - 749-757
IS - 6
VL - 58
SN - 0023-1584
SN - 1608-3210
ER -
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@article{2017_Titova,
author = {Yu Yu Titova and F.K Shmidt},
title = {Role of Water in the Catalysis of Ethylene Di- and Oligomerization and Toluene Alkylation Reactions Based on Nickel Bis(Acetylacetonate) Systems},
journal = {Kinetics and Catalysis},
year = {2017},
volume = {58},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/s0023158417050214},
number = {6},
pages = {749--757},
doi = {10.1134/s0023158417050214}
}
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Titova, Yu. Yu., and F.K Shmidt. “Role of Water in the Catalysis of Ethylene Di- and Oligomerization and Toluene Alkylation Reactions Based on Nickel Bis(Acetylacetonate) Systems.” Kinetics and Catalysis, vol. 58, no. 6, Nov. 2017, pp. 749-757. https://doi.org/10.1134/s0023158417050214.