Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate
Publication type: Journal Article
Publication date: 2019-05-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
Norbornadiene allylation by allyl formate in the presence of palladium catalytic systems has a number of features associated with different directions of β-hydride transfer in key intermediates, which can be carried out with the participation of allyl, norbornenyl, or formyl fragments. The value of the kinetic isotope effect and the nature of the limiting step in the reaction of hydroallylation of norbornadiene are determined using deuterated reagents.
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Durakov S. A. et al. Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate // Kinetics and Catalysis. 2019. Vol. 60. No. 3. pp. 245-249.
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Durakov S. A., Shamsiev R. S., Flid V. R., Gekhman A. E. Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate // Kinetics and Catalysis. 2019. Vol. 60. No. 3. pp. 245-249.
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RIS
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TY - JOUR
DO - 10.1134/S0023158419030042
UR - https://doi.org/10.1134/S0023158419030042
TI - Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate
T2 - Kinetics and Catalysis
AU - Durakov, S A
AU - Shamsiev, R S
AU - Flid, V R
AU - Gekhman, A E
PY - 2019
DA - 2019/05/01
PB - Pleiades Publishing
SP - 245-249
IS - 3
VL - 60
SN - 0023-1584
SN - 1608-3210
ER -
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BibTex (up to 50 authors)
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@article{2019_Durakov,
author = {S A Durakov and R S Shamsiev and V R Flid and A E Gekhman},
title = {Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate},
journal = {Kinetics and Catalysis},
year = {2019},
volume = {60},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S0023158419030042},
number = {3},
pages = {245--249},
doi = {10.1134/S0023158419030042}
}
Cite this
MLA
Copy
Durakov, S. A., et al. “Isotope Effect in Catalytic Hydroallylation of Norbornadiene by Allyl Formate.” Kinetics and Catalysis, vol. 60, no. 3, May. 2019, pp. 245-249. https://doi.org/10.1134/S0023158419030042.