Kinetics and Catalysis, volume 61, issue 4, pages 569-574

Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide

O M Chukanova 1
, 
K O Korenkov 2
, 
N O Garifullin 1
, 
O G Sheverdenkina 1
, 
I V Sedov 1, 2
1
 
2
 
Faculty of Fundamental Physical and Chemical Engineering, Moscow State University, Moscow, Russia | 
Publication type: Journal Article
Publication date: 2020-07-01
Q3
Q4
SJR: 0.254
CiteScore: 2.1
Impact factor: 1.3
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The kinetics of terpolymerization of CO2 with propylene oxide and hexene oxide in the presence of a binary catalytic system salenCoDNP/PPNCl was studied for the first time. The reaction rate was determined by measuring the CO2 uptake with time during terpolymerization. The dependences of the reaction rate and terpolymer composition on the mole fractions of epoxides in the feed were presented. The relationship between the rate constants of the insertion of various epoxides in the copolymers was determined. The glass transition temperatures of aliphatic polycarbonates depend on their composition and varied from 26.3 to –9.8°С.
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Chukanova O. M. et al. Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide // Kinetics and Catalysis. 2020. Vol. 61. No. 4. pp. 569-574.
GOST all authors (up to 50) Copy
Chukanova O. M., Korenkov K. O., Garifullin N. O., Sheverdenkina O. G., Sedov I. V. Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide // Kinetics and Catalysis. 2020. Vol. 61. No. 4. pp. 569-574.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/s0023158420030088
UR - https://doi.org/10.1134/s0023158420030088
TI - Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide
T2 - Kinetics and Catalysis
AU - Chukanova, O M
AU - Korenkov, K O
AU - Garifullin, N O
AU - Sheverdenkina, O G
AU - Sedov, I V
PY - 2020
DA - 2020/07/01
PB - Pleiades Publishing
SP - 569-574
IS - 4
VL - 61
SN - 0023-1584
SN - 1608-3210
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2020_Chukanova,
author = {O M Chukanova and K O Korenkov and N O Garifullin and O G Sheverdenkina and I V Sedov},
title = {Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide},
journal = {Kinetics and Catalysis},
year = {2020},
volume = {61},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/s0023158420030088},
number = {4},
pages = {569--574},
doi = {10.1134/s0023158420030088}
}
MLA
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Chukanova, O. M., et al. “Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide.” Kinetics and Catalysis, vol. 61, no. 4, Jul. 2020, pp. 569-574. https://doi.org/10.1134/s0023158420030088.
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