Pleiades Publishing
Kinetics and Catalysis
,  том 61 ,  издание 4 ,  страницы 569-574

Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide

Тип публикации: Journal Article
Дата публикации: 2020-07-01
Pleiades Publishing
scimago Q3
wos Q4
БС2
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Краткое описание
The kinetics of terpolymerization of CO2 with propylene oxide and hexene oxide in the presence of a binary catalytic system salenCoDNP/PPNCl was studied for the first time. The reaction rate was determined by measuring the CO2 uptake with time during terpolymerization. The dependences of the reaction rate and terpolymer composition on the mole fractions of epoxides in the feed were presented. The relationship between the rate constants of the insertion of various epoxides in the copolymers was determined. The glass transition temperatures of aliphatic polycarbonates depend on their composition and varied from 26.3 to –9.8°С.
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Russian Chemical Reviews
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Chukanova O. M. et al. Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide // Kinetics and Catalysis. 2020. Vol. 61. No. 4. pp. 569-574.
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Chukanova O. M., Korenkov K. O., Garifullin N. O., Sheverdenkina O. G., Sedov I. V. Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide // Kinetics and Catalysis. 2020. Vol. 61. No. 4. pp. 569-574.
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TY - JOUR
DO - 10.1134/s0023158420030088
UR - https://doi.org/10.1134/s0023158420030088
TI - Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide
T2 - Kinetics and Catalysis
AU - Chukanova, O M
AU - Korenkov, K O
AU - Garifullin, N O
AU - Sheverdenkina, O G
AU - Sedov, I V
PY - 2020
DA - 2020/07/01
PB - Pleiades Publishing
SP - 569-574
IS - 4
VL - 61
SN - 0023-1584
SN - 1608-3210
ER -
BibTex |
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@article{2020_Chukanova,
author = {O M Chukanova and K O Korenkov and N O Garifullin and O G Sheverdenkina and I V Sedov},
title = {Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide},
journal = {Kinetics and Catalysis},
year = {2020},
volume = {61},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/s0023158420030088},
number = {4},
pages = {569--574},
doi = {10.1134/s0023158420030088}
}
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Chukanova, O. M., et al. “Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide.” Kinetics and Catalysis, vol. 61, no. 4, Jul. 2020, pp. 569-574. https://doi.org/10.1134/s0023158420030088.