High-Selective Catalyst Based on Intermetallic Rh1 In1 Particles for Nitrobenzene Hydrogenation
A V Rassolov
1
,
G. A. Ivanov
1
,
G O Bragina
1
,
G N Baeva
1
,
N S Smirnova
1
,
A. V. Kazakov
1
,
N Ya Usachev
1
,
A.Yu Stakheev
1
Publication type: Journal Article
Publication date: 2021-09-25
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The catalytic performance of a bimetallic RhIn/SiO2 catalyst was studied in the liquid-phase hydrogenation of nitrobenzene. The formation of intermetallic Rh1In1 nanoparticles was revealed by X-ray diffraction (XRD) analysis and confirmed by transmission electron microscopy (TEM) and IR spectroscopy of adsorbed CO. It was shown that, in comparison with monometallic Rh/SiO2, the hydrogenation of nitrobenzene on the RhIn/SiO2 catalyst proceeded at a higher rate and with higher selectivity. In contrast to the monometallic catalyst, the formation of by-products and the hydrogenation of the benzene ring did not proceed on the intermetallic sample. It was assumed that the higher selectivity of RhIn/SiO2 can be associated both with a change in the electronic state of Rh atoms and with the geometry of the active sites.
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7
Total citations:
7
Citations from 2025:
2
(33.33%)
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Rassolov A. V. et al. High-Selective Catalyst Based on Intermetallic Rh1In1 Particles for Nitrobenzene Hydrogenation // Kinetics and Catalysis. 2021. Vol. 62. No. 5. pp. 641-650.
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Rassolov A. V., Ivanov G. A., Bragina G. O., Baeva G. N., Smirnova N. S., Kazakov A. V., Usachev N. Ya., Stakheev A. High-Selective Catalyst Based on Intermetallic Rh1In1 Particles for Nitrobenzene Hydrogenation // Kinetics and Catalysis. 2021. Vol. 62. No. 5. pp. 641-650.
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RIS
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TY - JOUR
DO - 10.1134/S0023158421050062
UR - https://doi.org/10.1134/S0023158421050062
TI - High-Selective Catalyst Based on Intermetallic Rh1In1 Particles for Nitrobenzene Hydrogenation
T2 - Kinetics and Catalysis
AU - Rassolov, A V
AU - Ivanov, G. A.
AU - Bragina, G O
AU - Baeva, G N
AU - Smirnova, N S
AU - Kazakov, A. V.
AU - Usachev, N Ya
AU - Stakheev, A.Yu
PY - 2021
DA - 2021/09/25
PB - Pleiades Publishing
SP - 641-650
IS - 5
VL - 62
SN - 0023-1584
SN - 1608-3210
ER -
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BibTex (up to 50 authors)
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@article{2021_Rassolov,
author = {A V Rassolov and G. A. Ivanov and G O Bragina and G N Baeva and N S Smirnova and A. V. Kazakov and N Ya Usachev and A.Yu Stakheev},
title = {High-Selective Catalyst Based on Intermetallic Rh1In1 Particles for Nitrobenzene Hydrogenation},
journal = {Kinetics and Catalysis},
year = {2021},
volume = {62},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S0023158421050062},
number = {5},
pages = {641--650},
doi = {10.1134/S0023158421050062}
}
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MLA
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Rassolov, A. V., et al. “High-Selective Catalyst Based on Intermetallic Rh1In1 Particles for Nitrobenzene Hydrogenation.” Kinetics and Catalysis, vol. 62, no. 5, Sep. 2021, pp. 641-650. https://doi.org/10.1134/S0023158421050062.
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