Interaction of neptunyl with goethite (α-FeOOH), maghemite (γ-Fe2 O3 ), and hematite (α-Fe 2 O3 ) in water as probed by X-ray photoelectron spectroscopy
A.Yu. Teterin
1
,
K I Maslakov
2
,
Yu.A. Teterin
2
,
S N Kalmykov
3
,
K.E. Ivanov
2
,
L. Vukcevic
4
,
A B Khasanova
3
,
N S Shcherbina
3
Тип публикации: Journal Article
Дата публикации: 2006-12-12
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
The sorption behavior is studied and the physicochemical neptunium species existing on the surface of goethite (α-FeOOH), maghemite (γ-Fe2O3), and hematite (α-Fe2O3) are determined. Solvent extraction and X-ray photoelectron spectroscopy (XPS) are used to determine the neptunium surface species. The ion and elemental composition of the surface of the minerals and surface neptunyl NpO2+ complexes is determined using these data. Compounds containing neptunium(IV) or neptunium(VI) ions do not appear; rather, neptunyl (Np(V)O2+ group is complexed with surface hydroxide groups of α-FeOOH, γ-Fe2O3, and α-Fe2O3. Presumably, the oxygen atoms of iron oxides and water and/or carbonate (CO32-) or nitrate (NO3-) group lie in the equatorial plane of the neptunyl (NpO2+) group.
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Teterin A. et al. Interaction of neptunyl with goethite (α-FeOOH), maghemite (γ-Fe2O3), and hematite (α-Fe 2O3) in water as probed by X-ray photoelectron spectroscopy // Russian Journal of Inorganic Chemistry. 2006. Vol. 51. No. 12. pp. 1937-1944.
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Teterin A., Maslakov K. I., Teterin Y., Kalmykov S. N., Ivanov K., Vukcevic L., Khasanova A. B., Shcherbina N. S. Interaction of neptunyl with goethite (α-FeOOH), maghemite (γ-Fe2O3), and hematite (α-Fe 2O3) in water as probed by X-ray photoelectron spectroscopy // Russian Journal of Inorganic Chemistry. 2006. Vol. 51. No. 12. pp. 1937-1944.
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TY - JOUR
DO - 10.1134/S0036023606120151
UR - https://doi.org/10.1134/S0036023606120151
TI - Interaction of neptunyl with goethite (α-FeOOH), maghemite (γ-Fe2O3), and hematite (α-Fe 2O3) in water as probed by X-ray photoelectron spectroscopy
T2 - Russian Journal of Inorganic Chemistry
AU - Teterin, A.Yu.
AU - Maslakov, K I
AU - Teterin, Yu.A.
AU - Kalmykov, S N
AU - Ivanov, K.E.
AU - Vukcevic, L.
AU - Khasanova, A B
AU - Shcherbina, N S
PY - 2006
DA - 2006/12/12
PB - Pleiades Publishing
SP - 1937-1944
IS - 12
VL - 51
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (до 50 авторов)
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@article{2006_Teterin,
author = {A.Yu. Teterin and K I Maslakov and Yu.A. Teterin and S N Kalmykov and K.E. Ivanov and L. Vukcevic and A B Khasanova and N S Shcherbina},
title = {Interaction of neptunyl with goethite (α-FeOOH), maghemite (γ-Fe2O3), and hematite (α-Fe 2O3) in water as probed by X-ray photoelectron spectroscopy},
journal = {Russian Journal of Inorganic Chemistry},
year = {2006},
volume = {51},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S0036023606120151},
number = {12},
pages = {1937--1944},
doi = {10.1134/S0036023606120151}
}
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MLA
Скопировать
Teterin, A.Yu., et al. “Interaction of neptunyl with goethite (α-FeOOH), maghemite (γ-Fe2O3), and hematite (α-Fe 2O3) in water as probed by X-ray photoelectron spectroscopy.” Russian Journal of Inorganic Chemistry, vol. 51, no. 12, Dec. 2006, pp. 1937-1944. https://doi.org/10.1134/S0036023606120151.