Reaction of the closo-decaborate anion B10H 10 2− with dichloroethane in the presence of hydrogen halides
Тип публикации: Journal Article
Дата публикации: 2007-07-25
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
The reactions of the closo-decaborate anion with hydrogen halides and dichloroethane have been studied. Irrespective of the hydrogen halide used (HCl, HBr, HI), chlorination to give mono-, di-, and trihalosubstituted products is the major process. The product ratio depends on the hydrogen halide used and on the synthesis temperature and time. The products have been identified by 11B NMR, IR, and ESI mass spectra. The structure of (Ph3(NaphCH2)P)2B10H8Cl2 has been studied by X-ray diffraction. The geometry distortion of the closo-decaborate core found in the chlorinated derivatives is retained on further chemical transformations of the compound.
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Drozdova V. V. et al. Reaction of the closo-decaborate anion B10H 10 2− with dichloroethane in the presence of hydrogen halides // Russian Journal of Inorganic Chemistry. 2007. Vol. 52. No. 7. pp. 996-1001.
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Drozdova V. V., Zhizhin K. Yu., Malinina E. A., Polyakova I. N., Kuznetsov N. T. Reaction of the closo-decaborate anion B10H 10 2− with dichloroethane in the presence of hydrogen halides // Russian Journal of Inorganic Chemistry. 2007. Vol. 52. No. 7. pp. 996-1001.
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TY - JOUR
DO - 10.1134/S0036023607070042
UR - https://doi.org/10.1134/S0036023607070042
TI - Reaction of the closo-decaborate anion B10H 10 2− with dichloroethane in the presence of hydrogen halides
T2 - Russian Journal of Inorganic Chemistry
AU - Drozdova, V V
AU - Zhizhin, K Yu
AU - Malinina, E. A.
AU - Polyakova, I N
AU - Kuznetsov, N. T.
PY - 2007
DA - 2007/07/25
PB - Pleiades Publishing
SP - 996-1001
IS - 7
VL - 52
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2007_Drozdova,
author = {V V Drozdova and K Yu Zhizhin and E. A. Malinina and I N Polyakova and N. T. Kuznetsov},
title = {Reaction of the closo-decaborate anion B10H 10 2− with dichloroethane in the presence of hydrogen halides},
journal = {Russian Journal of Inorganic Chemistry},
year = {2007},
volume = {52},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0036023607070042},
number = {7},
pages = {996--1001},
doi = {10.1134/S0036023607070042}
}
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Drozdova, V. V., et al. “Reaction of the closo-decaborate anion B10H 10 2− with dichloroethane in the presence of hydrogen halides.” Russian Journal of Inorganic Chemistry, vol. 52, no. 7, Jul. 2007, pp. 996-1001. https://doi.org/10.1134/S0036023607070042.
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