Pleiades Publishing
Russian Journal of Inorganic Chemistry
,  том 53 ,  издание 8 ,  страницы 1187-1192

Peroxide derivatives of heteropoly compounds with Keggin anions [PW 12O40]3- and [SiW12O 40]4-: Synthesis and structure

Тип публикации: Journal Article
Дата публикации: 2008-08-12
Pleiades Publishing
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ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Peroxide derivatives of heteropoly compounds with Keggin anions [PW12O40]3− and [SiW12O40]4− are isolated in an individual state from concentrated hydrogen peroxide solutions and characterized by physicochemical methods. The structure of Ba2[SiW12O40] · 4H2O2 · 11H2O (I) is solved by X-ray crystallography. Crystals of compound I (H30Ba2O59Si1W12, FW = 3483.21) are monoclinic, space group C2/c, a = 24.981(2) Å, b = 12.2103(11) Å, c = 18.7142(17) Å, β = 122.620(2)o, V = 4808.0(8) Å3, Z = 4. The structure contains Keggin anions [SiW12O40]4−; all hydrogen peroxide molecules are coordinated to Ba2+ cations.
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Churakov A. et al. Peroxide derivatives of heteropoly compounds with Keggin anions [PW 12O40]3- and [SiW12O 40]4-: Synthesis and structure // Russian Journal of Inorganic Chemistry. 2008. Vol. 53. No. 8. pp. 1187-1192.
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Churakov A., Legurova E. A., Dutov A. A., Prikhodchenko P. V., Tripolskaya T. A. Peroxide derivatives of heteropoly compounds with Keggin anions [PW 12O40]3- and [SiW12O 40]4-: Synthesis and structure // Russian Journal of Inorganic Chemistry. 2008. Vol. 53. No. 8. pp. 1187-1192.
RIS |
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TY - JOUR
DO - 10.1134/S0036023608080068
UR - http://link.springer.com/10.1134/S0036023608080068
TI - Peroxide derivatives of heteropoly compounds with Keggin anions [PW 12O40]3- and [SiW12O 40]4-: Synthesis and structure
T2 - Russian Journal of Inorganic Chemistry
AU - Churakov, A.V.
AU - Legurova, E A
AU - Dutov, A A
AU - Prikhodchenko, P V
AU - Tripolskaya, T A
PY - 2008
DA - 2008/08/12
PB - Pleiades Publishing
SP - 1187-1192
IS - 8
VL - 53
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2008_Churakov,
author = {A.V. Churakov and E A Legurova and A A Dutov and P V Prikhodchenko and T A Tripolskaya},
title = {Peroxide derivatives of heteropoly compounds with Keggin anions [PW 12O40]3- and [SiW12O 40]4-: Synthesis and structure},
journal = {Russian Journal of Inorganic Chemistry},
year = {2008},
volume = {53},
publisher = {Pleiades Publishing},
month = {aug},
url = {http://link.springer.com/10.1134/S0036023608080068},
number = {8},
pages = {1187--1192},
doi = {10.1134/S0036023608080068}
}
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Churakov, A.V., et al. “Peroxide derivatives of heteropoly compounds with Keggin anions [PW 12O40]3- and [SiW12O 40]4-: Synthesis and structure.” Russian Journal of Inorganic Chemistry, vol. 53, no. 8, Aug. 2008, pp. 1187-1192. http://link.springer.com/10.1134/S0036023608080068.
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