On the nature of the chemical bond in heterobimetallic palladium(II) complexes with divalent 3d metals
A. A. Markov
1
,
A P Klyagina
1
,
S P Dolin
1
,
N S Akhmadullina
1
,
N.Yu. Kozitsyna
1
,
N V Cherkashina
1
,
S.E. Nefedov
1
,
M.N. Vargaftik
1
,
I. I. Moiseev
1
Publication type: Journal Article
Publication date: 2009-06-22
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The complex Pd(μ-OOCMe)4Cu(OH2) · 2Pd3(μ-OOCMe)6 was synthesized and characterized by X-ray crystallography. In the heterometallic moiety of this complex, the PdII and CuII atoms are at an extraordinary short distance (2.521(3) Å). DFT quantum-chemical calculations of the geometric and electronic structure of a series of heterobinuclear paddlewheel complexes PdIIMII(μ-OOCMe)4L (M = ZnII, NiII, CuII, CoII, FeII; L = OH2 and NCH) and their formate analogues PdIIMII(μ-OOCH)4L (M = ZnII, NiII, FeII) showed that the extraordinary short Pd⋯M distance in all these complexes is caused only by the tightening effect of carboxylate bridges rather than by the metal-metal bond. The direct Pd-M interaction becomes possible only after removal of electrons from the antibonding orbitals and formation of oxidized complexes of the [PdIII(μ-OOCMe)4NiIII]2+ type.
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Markov A. A. et al. On the nature of the chemical bond in heterobimetallic palladium(II) complexes with divalent 3d metals // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 6. pp. 885-892.
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Markov A. A., Klyagina A. P., Dolin S. P., Akhmadullina N. S., Kozitsyna N., Cherkashina N. V., Nefedov S., Vargaftik M., Moiseev I. I. On the nature of the chemical bond in heterobimetallic palladium(II) complexes with divalent 3d metals // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 6. pp. 885-892.
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RIS
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TY - JOUR
DO - 10.1134/S0036023609060114
UR - http://link.springer.com/10.1134/S0036023609060114
TI - On the nature of the chemical bond in heterobimetallic palladium(II) complexes with divalent 3d metals
T2 - Russian Journal of Inorganic Chemistry
AU - Markov, A. A.
AU - Klyagina, A P
AU - Dolin, S P
AU - Akhmadullina, N S
AU - Kozitsyna, N.Yu.
AU - Cherkashina, N V
AU - Nefedov, S.E.
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2009
DA - 2009/06/22
PB - Pleiades Publishing
SP - 885-892
IS - 6
VL - 54
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2009_Markov,
author = {A. A. Markov and A P Klyagina and S P Dolin and N S Akhmadullina and N.Yu. Kozitsyna and N V Cherkashina and S.E. Nefedov and M.N. Vargaftik and I. I. Moiseev},
title = {On the nature of the chemical bond in heterobimetallic palladium(II) complexes with divalent 3d metals},
journal = {Russian Journal of Inorganic Chemistry},
year = {2009},
volume = {54},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S0036023609060114},
number = {6},
pages = {885--892},
doi = {10.1134/S0036023609060114}
}
Cite this
MLA
Copy
Markov, A. A., et al. “On the nature of the chemical bond in heterobimetallic palladium(II) complexes with divalent 3d metals.” Russian Journal of Inorganic Chemistry, vol. 54, no. 6, Jun. 2009, pp. 885-892. http://link.springer.com/10.1134/S0036023609060114.