Synthesis and structure of mononuclear molecular complexes of molybdenum(VI) and tungsten(VI) oxy- and dioxyhalides
Publication type: Journal Article
Publication date: 2009-12-05
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Specific features of the synthesis and structure of mononuclear molecular halide oxide complexes of Group VI d0 metals molybdenum(VI) and tungsten(VI) are surveyed. Various methods of synthesis of adducts based on MOX4 and MO2X2 (M = Mo, W; X = F, Cl, Br) are described, such as direct interaction, ligand exchange, and the method of nascent reagents. The principles of formation of a particular geometric isomer are discussed: according to the self-consistency rule, the coordination of a neutral donor ligand L trans to a multiply bonded oxo ligand is preferable to that of acido ligands X− (anions). Rare exceptions are mentioned.
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GOST
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Abramenko V. L., Sergienko V. S. Synthesis and structure of mononuclear molecular complexes of molybdenum(VI) and tungsten(VI) oxy- and dioxyhalides // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 13. pp. 2031-2053.
GOST all authors (up to 50)
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Abramenko V. L., Sergienko V. S. Synthesis and structure of mononuclear molecular complexes of molybdenum(VI) and tungsten(VI) oxy- and dioxyhalides // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 13. pp. 2031-2053.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S0036023609130014
UR - https://doi.org/10.1134/S0036023609130014
TI - Synthesis and structure of mononuclear molecular complexes of molybdenum(VI) and tungsten(VI) oxy- and dioxyhalides
T2 - Russian Journal of Inorganic Chemistry
AU - Abramenko, V L
AU - Sergienko, V S
PY - 2009
DA - 2009/12/05
PB - Pleiades Publishing
SP - 2031-2053
IS - 13
VL - 54
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Abramenko,
author = {V L Abramenko and V S Sergienko},
title = {Synthesis and structure of mononuclear molecular complexes of molybdenum(VI) and tungsten(VI) oxy- and dioxyhalides},
journal = {Russian Journal of Inorganic Chemistry},
year = {2009},
volume = {54},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S0036023609130014},
number = {13},
pages = {2031--2053},
doi = {10.1134/S0036023609130014}
}
Cite this
MLA
Copy
Abramenko, V. L., and V S Sergienko. “Synthesis and structure of mononuclear molecular complexes of molybdenum(VI) and tungsten(VI) oxy- and dioxyhalides.” Russian Journal of Inorganic Chemistry, vol. 54, no. 13, Dec. 2009, pp. 2031-2053. https://doi.org/10.1134/S0036023609130014.
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