Li+/H+ ion exchange in Li3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) materials with a NASICON structure
Publication type: Journal Article
Publication date: 2010-01-20
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
H3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) acid phosphates have been obtained by ion exchange from their lithium forms and X-ray powder diffraction, impedance measurements, and 7Li and 1H NMR spectroscopy. The parameters of the hexagonal unit cell of the proton-exchanged forms differ only slightly from those of the initial lithium compounds. According to 1H NMR data, the proton in the acid phosphates is not hydrated. The conductivity of the acid phosphates at high temperatures depends weakly on their composition and is ∼1.7 × 10−7 S cm−1 at 620 K. The activation energy of conduction is 30–33 kJ/mol (430–770 K).
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Shaikhlislamova A. R., ZHURAVLEV N., Yaroslavtsev A. B. Li+/H+ ion exchange in Li3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) materials with a NASICON structure // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 1. pp. 18-22.
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Shaikhlislamova A. R., ZHURAVLEV N., Yaroslavtsev A. B. Li+/H+ ion exchange in Li3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) materials with a NASICON structure // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 1. pp. 18-22.
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TY - JOUR
DO - 10.1134/S0036023610010043
UR - http://link.springer.com/10.1134/S0036023610010043
TI - Li+/H+ ion exchange in Li3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) materials with a NASICON structure
T2 - Russian Journal of Inorganic Chemistry
AU - Shaikhlislamova, A R
AU - ZHURAVLEV, N.A.
AU - Yaroslavtsev, A. B.
PY - 2010
DA - 2010/01/20
PB - Pleiades Publishing
SP - 18-22
IS - 1
VL - 55
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2010_Shaikhlislamova,
author = {A R Shaikhlislamova and N.A. ZHURAVLEV and A. B. Yaroslavtsev},
title = {Li+/H+ ion exchange in Li3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) materials with a NASICON structure},
journal = {Russian Journal of Inorganic Chemistry},
year = {2010},
volume = {55},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S0036023610010043},
number = {1},
pages = {18--22},
doi = {10.1134/S0036023610010043}
}
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Shaikhlislamova, A. R., et al. “Li+/H+ ion exchange in Li3 − 2x Nb x M2 − x (PO4)3 (M = In, Fe) materials with a NASICON structure.” Russian Journal of Inorganic Chemistry, vol. 55, no. 1, Jan. 2010, pp. 18-22. http://link.springer.com/10.1134/S0036023610010043.
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