Russian Journal of Inorganic Chemistry

, том 55 , издание 3 , страницы 318-324

Diffusion mobility of alkali metals in perfluorinated sulfocationic and carboxylic membranes as probed by 1H, 7Li, 23Na, and 133Cs NMR spectroscopy

V. I. Volkov ¹

E V Volkov ¹

S.V Timofeev ²

E A Sanginov ¹

A. A. Pavlov ¹

E. Yu. Safronova ³

I A Stenina ³

A. B. Yaroslavtsev ³

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia |

Plastpolimer, St. Petersburg, Russia |

Kurnakov institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2010-03-01

Pleiades Publishing

Russian Journal of Inorganic Chemistry

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wos Q4

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SJR: 0.270

CiteScore: 3.0

Impact factor: 1.5

ISSN: 00360236, 15318613

DOI: 10.1134/S0036023610030022

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Inorganic Chemistry

Physical and Theoretical Chemistry

Materials Science (miscellaneous)

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The hydration, state, and ion mobility of protons and alkali metal cations (Li+, Na+, and Cs+) in perfluorinated sulfocationic membranes (MF-4SK) and carboxylic membranes (F-4KF) were studied using NMR and impedance spectroscopy. The hydration numbers and translational mobilities of ions and the formation conditions for cation/ionogenic group tight ion pairs were ascertained proceeding from analysis of chemical shifts and 1H, 7Li, 23Na, and 133Cs NMR line widths. NMR data correlate with the results of ion conductivity measurements. The translational mobility of cations and ionic conductivity in the sulfocationic membranes are higher than in the carboxylic membranes and increase in the order Cs+-Na+-Li+.

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Volkov V. I. et al. Diffusion mobility of alkali metals in perfluorinated sulfocationic and carboxylic membranes as probed by 1H, 7Li, 23Na, and 133Cs NMR spectroscopy // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 3. pp. 318-324.

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Volkov V. I., Volkov E. V., Timofeev S., Sanginov E. A., Pavlov A. A., Safronova E. Y., Stenina I. A., Yaroslavtsev A. B. Diffusion mobility of alkali metals in perfluorinated sulfocationic and carboxylic membranes as probed by 1H, 7Li, 23Na, and 133Cs NMR spectroscopy // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 3. pp. 318-324.

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TY - JOUR

DO - 10.1134/S0036023610030022

UR - http://link.springer.com/10.1134/S0036023610030022

TI - Diffusion mobility of alkali metals in perfluorinated sulfocationic and carboxylic membranes as probed by 1H, 7Li, 23Na, and 133Cs NMR spectroscopy

T2 - Russian Journal of Inorganic Chemistry

AU - Volkov, V. I.

AU - Volkov, E V

AU - Timofeev, S.V

AU - Sanginov, E A

AU - Pavlov, A. A.

AU - Safronova, E. Yu.

AU - Stenina, I A

AU - Yaroslavtsev, A. B.

PY - 2010

DA - 2010/03/01

PB - Pleiades Publishing

SP - 318-324

IS - 3

VL - 55

SN - 0036-0236

SN - 1531-8613

ER -

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@article{2010_Volkov,

author = {V. I. Volkov and E V Volkov and S.V Timofeev and E A Sanginov and A. A. Pavlov and E. Yu. Safronova and I A Stenina and A. B. Yaroslavtsev},

title = {Diffusion mobility of alkali metals in perfluorinated sulfocationic and carboxylic membranes as probed by 1H, 7Li, 23Na, and 133Cs NMR spectroscopy},

journal = {Russian Journal of Inorganic Chemistry},

year = {2010},

volume = {55},

publisher = {Pleiades Publishing},

month = {mar},

url = {http://link.springer.com/10.1134/S0036023610030022},

number = {3},

pages = {318--324},

doi = {10.1134/S0036023610030022}

}

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Volkov, V. I., et al. “Diffusion mobility of alkali metals in perfluorinated sulfocationic and carboxylic membranes as probed by 1H, 7Li, 23Na, and 133Cs NMR spectroscopy.” Russian Journal of Inorganic Chemistry, vol. 55, no. 3, Mar. 2010, pp. 318-324. http://link.springer.com/10.1134/S0036023610030022.