Russian Journal of Inorganic Chemistry, volume 55, issue 8, pages 1172-1178

Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3'-bis(dipyrromethene) hydrobromides

Publication typeJournal Article
Publication date2010-08-25
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
3,3′-Bis(dipyrromethene) dihydrobromides (H2L · 2HBr) with various types of alkylation have been synthesized. On the basis of IR, 1H NMR, and electronic absorption spectra, spectrophotometric titration, and thermogravimetry, conclusions have been drawn about the influence of structural factors on the optical and thermal properties and salt stability in solutions. An increase in the degree of alkylation causes a significant high-frequency shift of the N-H stretching vibration band in the IR spectra, an upfield shift of the 1H NMR signals of NH protons, a decrease in the auxochromic effects of protons on the aromatic system of the chromophore, and an increase in the salt stability in solutions in the presence of nucleophilic reagents and in the thermal stability in air and argon.

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GOST Copy
Antina E. V. et al. Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3'-bis(dipyrromethene) hydrobromides // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 8. pp. 1172-1178.
GOST all authors (up to 50) Copy
Antina E. V., Guseva G. B., Dudina N. A., Vyugin A. I. Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3'-bis(dipyrromethene) hydrobromides // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 8. pp. 1172-1178.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036023610080036
UR - https://doi.org/10.1134%2FS0036023610080036
TI - Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3'-bis(dipyrromethene) hydrobromides
T2 - Russian Journal of Inorganic Chemistry
AU - Dudina, N A
AU - Vyugin, A I
AU - Antina, E V
AU - Guseva, G B
PY - 2010
DA - 2010/08/25 00:00:00
PB - Pleiades Publishing
SP - 1172-1178
IS - 8
VL - 55
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
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BibTex Copy
@article{2010_Antina,
author = {N A Dudina and A I Vyugin and E V Antina and G B Guseva},
title = {Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3'-bis(dipyrromethene) hydrobromides},
journal = {Russian Journal of Inorganic Chemistry},
year = {2010},
volume = {55},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS0036023610080036},
number = {8},
pages = {1172--1178},
doi = {10.1134/S0036023610080036}
}
MLA
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MLA Copy
Antina, E. V., et al. “Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3'-bis(dipyrromethene) hydrobromides.” Russian Journal of Inorganic Chemistry, vol. 55, no. 8, Aug. 2010, pp. 1172-1178. https://doi.org/10.1134%2FS0036023610080036.
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