том 55 издание 9 страницы 1366-1372

The coordination polymer triaquabarium-μ-bis(citrato)germanate trihydrate: Synthesis, properties, and molecular and crystal structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H 2O} n

Тип публикацииJournal Article
Дата публикации2010-09-09
scimago Q3
wos Q4
БС2
SJR0.270
CiteScore3.0
Impact factor1.5
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
AbstractThe polymeric coordination compound {[Ge(μ-HCit)2Ba(H2O)3] · 3H2O}n (H4Cit = citric acid) was obtained for the first time for germanium(IV) citrates. The compound was characterized by elemental analysis, thermogravimetry, IR spectroscopy, and X-ray crystallography. Crystals of the compound are triclinic, a = 7.422(4) Å, b = 10.668(4) Å, c = 14.342(6) Å, α = 91.31(3)°, β = 95.81(4)°, γ = 104.08(4)°, V = 1094.5(8) Å3, Z = 2, space group P$$ \bar 1 $$, R1 = 0.0479 for 2284 reflections with I > 2σ(I). Two crystallographically independent octahedral [Ge(HCit)2]2− anions are linked by Ba2+ ions to form a polymeric chain. The coordination number of Ba atoms is equal to 9. The chains are linked to each other and crystal water molecules by hydrogen bonds.
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Pesaroglo A. G. et al. The coordination polymer triaquabarium-μ-bis(citrato)germanate trihydrate: Synthesis, properties, and molecular and crystal structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H 2O} n // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 9. pp. 1366-1372.
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Pesaroglo A. G., Martsinko E. É., Minacheva L. Kh., Seifullina I. I., Sergienko V. S. The coordination polymer triaquabarium-μ-bis(citrato)germanate trihydrate: Synthesis, properties, and molecular and crystal structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H 2O} n // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 9. pp. 1366-1372.
RIS |
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TY - JOUR
DO - 10.1134/S0036023610090068
UR - https://doi.org/10.1134/S0036023610090068
TI - The coordination polymer triaquabarium-μ-bis(citrato)germanate trihydrate: Synthesis, properties, and molecular and crystal structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H 2O} n
T2 - Russian Journal of Inorganic Chemistry
AU - Pesaroglo, A G
AU - Martsinko, E É
AU - Minacheva, L Kh
AU - Seifullina, I I
AU - Sergienko, V S
PY - 2010
DA - 2010/09/09
PB - Pleiades Publishing
SP - 1366-1372
IS - 9
VL - 55
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2010_Pesaroglo,
author = {A G Pesaroglo and E É Martsinko and L Kh Minacheva and I I Seifullina and V S Sergienko},
title = {The coordination polymer triaquabarium-μ-bis(citrato)germanate trihydrate: Synthesis, properties, and molecular and crystal structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H 2O} n},
journal = {Russian Journal of Inorganic Chemistry},
year = {2010},
volume = {55},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S0036023610090068},
number = {9},
pages = {1366--1372},
doi = {10.1134/S0036023610090068}
}
MLA
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Pesaroglo, A. G., et al. “The coordination polymer triaquabarium-μ-bis(citrato)germanate trihydrate: Synthesis, properties, and molecular and crystal structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H 2O} n.” Russian Journal of Inorganic Chemistry, vol. 55, no. 9, Sep. 2010, pp. 1366-1372. https://doi.org/10.1134/S0036023610090068.