Crystal and molecular structure of tetraaquabarium Di-μ-tartrato-di- μ-hydroxodigermanate(IV) pentahydrate [Ba(H2 O)4 ] [Ge2 (μ-Tart)2 (μ-OH)2 ] • 5H 2 O
1
Mechnikov National University, Odessa, Ukraine
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Publication type: Journal Article
Publication date: 2011-01-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
A new heteronuclear germanium barium complex with D-tartaric acid [Ba(H2O)4][Ge2(μ-Tart)2(μ-OH)2]·5H2O (I) (H4Tart is tartaric acid) was synthesized. The identity of compound I and its com- position were determined by elemental analysis and X-ray diffraction. The thermal stability of the compound was studied; the coordination centers of the ligand were found from IR spectroscopy. The structure of I was determined by X-ray crystallography. Crystals I are tetragonal: a = 8.5033(2) Å, c = 30.9393(11) Å, V = 2237.10(11) Å3, Z = 4, space group P41, R1 = 0.0301 based on 4215 reflections with I > 2σ(I). In crystals I, neutral [Ge2(μ-Tart)2] dimers are linked in pairs by double hydroxyl bridges to form {[Ge2(μ-Tart)2(μ-OH)2]2−}∞ polymeric chains. Hydrated Ba2+ cations and crystal water molecules are in between the anionic chains. Polymeric complex anions, hydrated barium cations, and H2O molecules are bound by a system of hydrogen bonds to form a framework.
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Martsinko E. É. et al. Crystal and molecular structure of tetraaquabarium Di-μ-tartrato-di- μ-hydroxodigermanate(IV) pentahydrate [Ba(H2O)4] [Ge2(μ-Tart)2(μ-OH)2] • 5H 2O // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 1. pp. 26-31.
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Martsinko E. É., Pesaroglo A. G., Minacheva L. Kh., Seifullina I. I., Sergienko V. S., Churakov A. Crystal and molecular structure of tetraaquabarium Di-μ-tartrato-di- μ-hydroxodigermanate(IV) pentahydrate [Ba(H2O)4] [Ge2(μ-Tart)2(μ-OH)2] • 5H 2O // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 1. pp. 26-31.
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TY - JOUR
DO - 10.1134/S0036023611010190
UR - http://link.springer.com/10.1134/S0036023611010190
TI - Crystal and molecular structure of tetraaquabarium Di-μ-tartrato-di- μ-hydroxodigermanate(IV) pentahydrate [Ba(H2O)4] [Ge2(μ-Tart)2(μ-OH)2] • 5H 2O
T2 - Russian Journal of Inorganic Chemistry
AU - Martsinko, E É
AU - Pesaroglo, A G
AU - Minacheva, L Kh
AU - Seifullina, I I
AU - Sergienko, V S
AU - Churakov, A.V.
PY - 2011
DA - 2011/01/01
PB - Pleiades Publishing
SP - 26-31
IS - 1
VL - 56
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2011_Martsinko,
author = {E É Martsinko and A G Pesaroglo and L Kh Minacheva and I I Seifullina and V S Sergienko and A.V. Churakov},
title = {Crystal and molecular structure of tetraaquabarium Di-μ-tartrato-di- μ-hydroxodigermanate(IV) pentahydrate [Ba(H2O)4] [Ge2(μ-Tart)2(μ-OH)2] • 5H 2O},
journal = {Russian Journal of Inorganic Chemistry},
year = {2011},
volume = {56},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S0036023611010190},
number = {1},
pages = {26--31},
doi = {10.1134/S0036023611010190}
}
Cite this
MLA
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Martsinko, E. É., et al. “Crystal and molecular structure of tetraaquabarium Di-μ-tartrato-di- μ-hydroxodigermanate(IV) pentahydrate [Ba(H2O)4] [Ge2(μ-Tart)2(μ-OH)2] • 5H 2O.” Russian Journal of Inorganic Chemistry, vol. 56, no. 1, Jan. 2011, pp. 26-31. http://link.springer.com/10.1134/S0036023611010190.