The role of water molecules in formation of heterometallic palladium acetate complexes with cerium and neodymium
S.E. Nefedov
1
,
N.Yu. Kozitsyna
1
,
N S Akhmadullina
1
,
N V Cherkashina
1
,
M.N. Vargaftik
1
,
I. I. Moiseev
1
Publication type: Journal Article
Publication date: 2011-03-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The reactions of palladium(II) acetate with neodymium(III) and cerium(III) acetates in acetic acid containing a specified amount of water have been studied. The following homo- and heterometallic complexes have been synthesized and characterized by X-ray diffraction: Nd2(μ-OOCMe)2(μ,η2-OOCMe)2(η2-OOCMe)2(HOOCMe)2(OH2)2 · 4HOOCMe, [Pd(μ-OOCMe)4Ce(OH2)2(μ,η2-OOCMe)]2 · 2HOOCMe · 6H2O, [Pd(μ-OOCMe)4Ce(OH2)2(μ,η2-OOCMe)]2 · 14H2O, [Pd(μ-OOCMe)4M(HOOCMe)2(OH2)2]+ [Pd(μ-OOCMe)4M(μ-OOCMe)4Pd]− · 2MeCOOH · 1.5H2O (M = Nd, Ce), and {[Pd(μ-OOCMe)4Ce(OOCMe)4]2 [Pd4(μ-OOCMe)4]2(μ4-O)8CePd4}(OH)3 · 27H2O. From kinetic and structural data and optical spectra of reaction solutions, the conclusion was drawn that hydrolytic processes play a decisive role in complexation reactions.
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Nefedov S. et al. The role of water molecules in formation of heterometallic palladium acetate complexes with cerium and neodymium // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 3. pp. 357-374.
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Nefedov S., Kozitsyna N., Akhmadullina N. S., Cherkashina N. V., Vargaftik M., Moiseev I. I. The role of water molecules in formation of heterometallic palladium acetate complexes with cerium and neodymium // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 3. pp. 357-374.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023611030156
UR - http://link.springer.com/10.1134/S0036023611030156
TI - The role of water molecules in formation of heterometallic palladium acetate complexes with cerium and neodymium
T2 - Russian Journal of Inorganic Chemistry
AU - Nefedov, S.E.
AU - Kozitsyna, N.Yu.
AU - Akhmadullina, N S
AU - Cherkashina, N V
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2011
DA - 2011/03/01
PB - Pleiades Publishing
SP - 357-374
IS - 3
VL - 56
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2011_Nefedov,
author = {S.E. Nefedov and N.Yu. Kozitsyna and N S Akhmadullina and N V Cherkashina and M.N. Vargaftik and I. I. Moiseev},
title = {The role of water molecules in formation of heterometallic palladium acetate complexes with cerium and neodymium},
journal = {Russian Journal of Inorganic Chemistry},
year = {2011},
volume = {56},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S0036023611030156},
number = {3},
pages = {357--374},
doi = {10.1134/S0036023611030156}
}
Cite this
MLA
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Nefedov, S.E., et al. “The role of water molecules in formation of heterometallic palladium acetate complexes with cerium and neodymium.” Russian Journal of Inorganic Chemistry, vol. 56, no. 3, Mar. 2011, pp. 357-374. http://link.springer.com/10.1134/S0036023611030156.
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