Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]−
Тип публикации: Journal Article
Дата публикации: 2011-06-29
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Compounds (Bu4N)[2-B10H9{NH=C(NHR)CH3}]− are obtained by reactions of the tetrabutylammonium salt of the [2-B10H9(N≡CCH3)]− anion with aliphatic and aromatic primary amines RNH2 (R = n-C3H7, n-C4H9, cyclo-C5H9, C6H5, cyclo-C6H11, n-C6H13, C7H7, C8H8NH2, C6H4NO2, and C18H37) and identified by IR, ESI/MS, and NMR (1H, 11B, and 13C) spectroscopy. The structures of the amidine-type derivatives [2-B10H9{Z-NH=C(NH-cyclo-C5H9)CH3}]− and [2-B10H9{Z-NH=C(NH-C7H7)CH3}]− are determined by X-ray diffraction.
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Zhdanov A. P. et al. Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]− // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 6. pp. 847-855.
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Zhdanov A. P., Polyakova I. N., Razgonyaeva G. A., Zhizhin K. Yu., Kuznetsov N. T. Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]− // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 6. pp. 847-855.
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TY - JOUR
DO - 10.1134/S003602361106026X
UR - https://doi.org/10.1134/S003602361106026X
TI - Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]−
T2 - Russian Journal of Inorganic Chemistry
AU - Zhdanov, A P
AU - Polyakova, I N
AU - Razgonyaeva, G A
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2011
DA - 2011/06/29
PB - Pleiades Publishing
SP - 847-855
IS - 6
VL - 56
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2011_Zhdanov,
author = {A P Zhdanov and I N Polyakova and G A Razgonyaeva and K Yu Zhizhin and N. T. Kuznetsov},
title = {Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]−},
journal = {Russian Journal of Inorganic Chemistry},
year = {2011},
volume = {56},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S003602361106026X},
number = {6},
pages = {847--855},
doi = {10.1134/S003602361106026X}
}
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MLA
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Zhdanov, A. P., et al. “Reactions of nucleophilic addition of primary amines to the nitrilium derivative of the closo-decaborate anion [2-B10H9(N≡CCH3)]−.” Russian Journal of Inorganic Chemistry, vol. 56, no. 6, Jun. 2011, pp. 847-855. https://doi.org/10.1134/S003602361106026X.
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