Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H8− and B12H122− anions
Publication type: Journal Article
Publication date: 2013-11-07
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
A new method for the synthesis of the B3H 8 − anion based on the reactions of alkyl and aryl halides (C2H4Cl2, C6H5CH2Cl, C4H9Br, (C6H5)3CCl, C10H7CH2Cl, CH2I2, C2HCl3) with sodium tetrahydroborate in diglyme was proposed. The method is characterized by high (up to quantitative) yields and easy isolation of the target products, (n-C4H9)4N)[B3H8] and Cs[B3H8], and also easy preparation of a salt of higher hydroborate anion, B12H 12 2− , without multistage purification from impurities of other anions of this series.
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Total citations:
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Citations from 2025:
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(21.05%)
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GOST
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Bykov A. Yu. et al. Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H8− and B12H122− anions // Russian Journal of Inorganic Chemistry. 2013. Vol. 58. No. 11. pp. 1321-1323.
GOST all authors (up to 50)
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Bykov A. Yu., Maltseva N. N., Generalova N. B., Zhizhin K. Yu., Kuznetsov N. T. Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H8− and B12H122− anions // Russian Journal of Inorganic Chemistry. 2013. Vol. 58. No. 11. pp. 1321-1323.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S003602361311003X
UR - https://doi.org/10.1134/S003602361311003X
TI - Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H8− and B12H122− anions
T2 - Russian Journal of Inorganic Chemistry
AU - Bykov, A Yu
AU - Maltseva, N N
AU - Generalova, N B
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2013
DA - 2013/11/07
PB - Pleiades Publishing
SP - 1321-1323
IS - 11
VL - 58
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Bykov,
author = {A Yu Bykov and N N Maltseva and N B Generalova and K Yu Zhizhin and N. T. Kuznetsov},
title = {Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H8− and B12H122− anions},
journal = {Russian Journal of Inorganic Chemistry},
year = {2013},
volume = {58},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S003602361311003X},
number = {11},
pages = {1321--1323},
doi = {10.1134/S003602361311003X}
}
Cite this
MLA
Copy
Bykov, A. Yu., et al. “Reactions of sodium tetrahydroborate with alkyl and aryl halides: A new approach to the synthesis of B3H8− and B12H122− anions.” Russian Journal of Inorganic Chemistry, vol. 58, no. 11, Nov. 2013, pp. 1321-1323. https://doi.org/10.1134/S003602361311003X.
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