Russian Journal of Inorganic Chemistry

, том 59 , издание 5 , страницы 446-454

Unusual sandwich platinum(II) complex: [Pt(phen)2]²⁺ cation between two Pt(phen)(OOCMe)2 molecules

Тип публикации: Journal Article

Дата публикации: 2014-05-23

Pleiades Publishing

Russian Journal of Inorganic Chemistry

scimago Q3

wos Q4

БС2

SJR: 0.270

CiteScore: 3.0

Impact factor: 1.5

ISSN: 00360236, 15318613

DOI: 10.1134/S0036023614050076

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Inorganic Chemistry

Physical and Theoretical Chemistry

Materials Science (miscellaneous)

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New carboxylate platinum(II) complexes: syn and anti isomers of Pt(phen)(OOCMe)2 molecular complex, [Pt(phen)(NCMe)2](O3SCF3)2, as well as unusual sandwich complex [Pt(phen)2]2+ · 2syn-[Pt(phen)(OOCMe)2] where [Pt(phen)2]2+ cation is inserted between two syn-Pt(phen)(OOCMe)2 molecules were synthesized and structurally characterized by X-ray diffraction analysis. As distinct from syn- and anti-Pt(phen)(OOCMe)2 and [Pt(phen)(NCMe)2](O3SCF3)2 complexes with flat phenanthroline ligand, the phen ligands in [Pt(phen)2]2+ cation have a curved configuration. Comparative DFT analysis of geometry of model structures phen, phen+, phenH+, and [Ptphen2]n+ (n = 1, 2) showed that electron removal from phen molecule had no effect on its geometry in both free state and platinum(II) complexes.

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Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 50% Russian Journal of Inorganic Chemistry 1 публикация, 50%
Координационная химия	Координационная химия, 1, 50% Координационная химия 1 публикация, 50%
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Cherkashina N. V. et al. Unusual sandwich platinum(II) complex: [Pt(phen)2]2+ cation between two Pt(phen)(OOCMe)2 molecules // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 5. pp. 446-454.

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Cherkashina N. V., Nefedov S., Uvarova M. A., Klyagina A. P., Markov A. A., Vargaftik M., Moiseev I. I. Unusual sandwich platinum(II) complex: [Pt(phen)2]2+ cation between two Pt(phen)(OOCMe)2 molecules // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 5. pp. 446-454.

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TY - JOUR

DO - 10.1134/S0036023614050076

UR - http://link.springer.com/10.1134/S0036023614050076

TI - Unusual sandwich platinum(II) complex: [Pt(phen)2]2+ cation between two Pt(phen)(OOCMe)2 molecules

T2 - Russian Journal of Inorganic Chemistry

AU - Cherkashina, N V

AU - Nefedov, S.E.

AU - Uvarova, M A

AU - Klyagina, A P

AU - Markov, A. A.

AU - Vargaftik, M.N.

AU - Moiseev, I. I.

PY - 2014

DA - 2014/05/23

PB - Pleiades Publishing

SP - 446-454

IS - 5

VL - 59

SN - 0036-0236

SN - 1531-8613

ER -

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@article{2014_Cherkashina,

author = {N V Cherkashina and S.E. Nefedov and M A Uvarova and A P Klyagina and A. A. Markov and M.N. Vargaftik and I. I. Moiseev},

title = {Unusual sandwich platinum(II) complex: [Pt(phen)2]2+ cation between two Pt(phen)(OOCMe)2 molecules},

journal = {Russian Journal of Inorganic Chemistry},

year = {2014},

volume = {59},

publisher = {Pleiades Publishing},

month = {may},

url = {http://link.springer.com/10.1134/S0036023614050076},

number = {5},

pages = {446--454},

doi = {10.1134/S0036023614050076}

}

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Cherkashina, N. V., et al. “Unusual sandwich platinum(II) complex: [Pt(phen)2]2+ cation between two Pt(phen)(OOCMe)2 molecules.” Russian Journal of Inorganic Chemistry, vol. 59, no. 5, May. 2014, pp. 446-454. http://link.springer.com/10.1134/S0036023614050076.