Russian Journal of Inorganic Chemistry, volume 59, issue 6, pages 578-586

Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes)

Publication typeJournal Article
Publication date2014-06-12
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The effect of the attachment position of a methylene spacer in 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethene) N4-ligands (H2L) on physicochemical properties of their dinuclear homoleptic helicates [Zn2L2], such as specific features of their molecular structure, luminescence spectral characteristics, lability in acid solutions, and thermal stability in an argon atmosphere, has been examined. It has been shown that the substitution of the biladiene-type helicand by its 2,3- and especially 3,3′-analogues leads to a considerable enhancement of the chromophoric properties, an increase (up to 30-fold) of the fluorescence quantum yield, and an increase in the stability of corresponding dinuclear helicates [Zn2L2].

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GOST Copy
Antina E. V. et al. Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes) // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 6. pp. 578-586.
GOST all authors (up to 50) Copy
Antina E. V., Antina L. A., Guseva G. B., Berezin M. B., Vyugin A. I., Semeikin A. S., Ksenofontov A. A. Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes) // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 6. pp. 578-586.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036023614060023
UR - https://doi.org/10.1134%2FS0036023614060023
TI - Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes)
T2 - Russian Journal of Inorganic Chemistry
AU - Berezin, M B
AU - Vyugin, A I
AU - Ksenofontov, A A
AU - Antina, E V
AU - Antina, L A
AU - Guseva, G B
AU - Semeikin, A S
PY - 2014
DA - 2014/06/12 00:00:00
PB - Pleiades Publishing
SP - 578-586
IS - 6
VL - 59
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
Cite this
BibTex Copy
@article{2014_Antina
author = {M B Berezin and A I Vyugin and A A Ksenofontov and E V Antina and L A Antina and G B Guseva and A S Semeikin},
title = {Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2014},
volume = {59},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134%2FS0036023614060023},
number = {6},
pages = {578--586},
doi = {10.1134/S0036023614060023}
}
MLA
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MLA Copy
Antina, E. V., et al. “Comparative analysis of physicochemical properties of dinuclear zinc(II) helicates with 2,2′-, 2,3′-, and 3,3′-bis(dipyrromethenes).” Russian Journal of Inorganic Chemistry, vol. 59, no. 6, Jun. 2014, pp. 578-586. https://doi.org/10.1134%2FS0036023614060023.
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