том 59 издание 6 страницы 571-577

Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles

Тип публикацииJournal Article
Дата публикации2014-06-12
scimago Q3
wos Q4
БС2
SJR0.270
CiteScore3.0
Impact factor1.5
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
A series of mixed-ligand cyclometalated iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles (where aryl is phenyl, 4-chlorophenyl, 4-(N,N-dimethylamino)phenyl, 3,4-dimethoxyphenyl, and 2-thienyl) and 11-carboxydipyrido[3,2-a:2′,3′-c]phenazine have been synthesized and characterized by 1H NMR and 31P NMR spectroscopy and mass spectrometry. The electron absorption spectra (EASs) of the complexes are observed to contain charge-transfer bands in the low-energy region (below 600 nm, ɛ ≈ (1–3) × 103 mol/(L cm)). The bands experience appreciable bathochromic shifts as the electron-donating properties of a benzimidazole ligand strengthen. The complexes manifest luminescence in the yellow-red spectral region. According to alternating current voltammetry data, reversible and quasi-reversible redox transitions (Eox ≈ 1.2–1.7 V with respect to SHE, CH3CN) are observed in solutions of the studied complexes.
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Russian Journal of Inorganic Chemistry
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Pleiades Publishing
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Bezzubov S. I., Dolzhenko V. D., Kiselev Yu. M. Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 6. pp. 571-577.
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Bezzubov S. I., Dolzhenko V. D., Kiselev Yu. M. Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 6. pp. 571-577.
RIS |
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TY - JOUR
DO - 10.1134/S0036023614060047
UR - https://doi.org/10.1134/S0036023614060047
TI - Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles
T2 - Russian Journal of Inorganic Chemistry
AU - Bezzubov, S I
AU - Dolzhenko, V D
AU - Kiselev, Yu M
PY - 2014
DA - 2014/06/12
PB - Pleiades Publishing
SP - 571-577
IS - 6
VL - 59
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2014_Bezzubov,
author = {S I Bezzubov and V D Dolzhenko and Yu M Kiselev},
title = {Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles},
journal = {Russian Journal of Inorganic Chemistry},
year = {2014},
volume = {59},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S0036023614060047},
number = {6},
pages = {571--577},
doi = {10.1134/S0036023614060047}
}
MLA
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Bezzubov, S. I., et al. “Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles.” Russian Journal of Inorganic Chemistry, vol. 59, no. 6, Jun. 2014, pp. 571-577. https://doi.org/10.1134/S0036023614060047.