Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether
S.E. Nefedov
1
,
M A Uvarova
1
,
M A Golubnichaya
1
,
N.Yu. Kozitsyna
1
,
D G Chikhichin
2
,
L G Kamalov
2
,
M.N. Vargaftik
1
,
I. I. Moiseev
1
1
2
Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
|
Publication type: Journal Article
Publication date: 2014-07-23
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
A reaction between palladium(II) acetate and aqueous cerium(III) acetate in acetic acid with subsequent boiling in benzene with excess pivalic acid is found to yield the complex Pd(μ-OOCBut)4Ce(OOCBut)(HOOCBut)3 (1). The liquid-phase thermolysis of complex 1 in dibenzyl ether (190°C) leads to the formation of the tetranuclear complex [Pd(μ-OOCBut)4Ce(HOOCBut)]2(μ-OOCBut)(μ-OH2) (2). The structure of the synthesized complexes is established by X-ray diffraction.
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Pleiades Publishing
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Nefedov S. et al. Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 7. pp. 733-737.
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Nefedov S., Uvarova M. A., Golubnichaya M. A., Kozitsyna N., Chikhichin D. G., Kamalov L. G., Vargaftik M., Moiseev I. I. Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 7. pp. 733-737.
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RIS
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TY - JOUR
DO - 10.1134/S0036023614070171
UR - http://link.springer.com/10.1134/S0036023614070171
TI - Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether
T2 - Russian Journal of Inorganic Chemistry
AU - Nefedov, S.E.
AU - Uvarova, M A
AU - Golubnichaya, M A
AU - Kozitsyna, N.Yu.
AU - Chikhichin, D G
AU - Kamalov, L G
AU - Vargaftik, M.N.
AU - Moiseev, I. I.
PY - 2014
DA - 2014/07/23
PB - Pleiades Publishing
SP - 733-737
IS - 7
VL - 59
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2014_Nefedov,
author = {S.E. Nefedov and M A Uvarova and M A Golubnichaya and N.Yu. Kozitsyna and D G Chikhichin and L G Kamalov and M.N. Vargaftik and I. I. Moiseev},
title = {Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether},
journal = {Russian Journal of Inorganic Chemistry},
year = {2014},
volume = {59},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S0036023614070171},
number = {7},
pages = {733--737},
doi = {10.1134/S0036023614070171}
}
Cite this
MLA
Copy
Nefedov, S.E., et al. “Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether.” Russian Journal of Inorganic Chemistry, vol. 59, no. 7, Jul. 2014, pp. 733-737. http://link.springer.com/10.1134/S0036023614070171.
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