Russian Journal of Inorganic Chemistry, volume 59, issue 10, pages 1187-1194

Synthesis, spectral-luminescent properties of B(III) and Zn(II) complexes with alkyl- and aryl-substituted dipyrrins and azadipyrrins

Publication typeJournal Article
Publication date2014-09-25
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Effect of complexing atom, molecular structure of dipyrrolylmethene and its aza analog on spectral-luminescent properties of heteroleptic boron(III) and homoleptic zinc(II) complexes with 3,3′,5,5′-tetramethyl-2,2′-dipyrrolylmethene, 3,3′,5,5′-tetraphenyl-2,2′-dipyrrolylmethene, and 3,3′,5,5′-tetraphenyl-ms-aza-2,2′-dipyrrolylmethene in organic solvent solutions was studied. The complexes were found to exhibit strong chromophore (λ = 350–690 nm, ɛ ∼ 105 L/mol cm) and fluorescent properties. Quantum yield (γfl) for fluoroborate complexes reaches 100% and is weakly dependent on medium nature. The value of γfl for phenyl- and alkyl-substituted zinc(II) dipyrrolylmethenates in nonpolar solvents is not higher 0.3 and 0.03, respectively; complete fluorescence quenching is observed in electron-donating solvents. Aza-substitution at the meso spacer causes considerable shift of electronic absorption and fluorescence spectra to the red region but completely quenches fluorescence of zinc(II) chelates and decreases γfl of boron(III) complex to 0.04.

Citations by journals

1
2
3
4
5
Journal of Molecular Liquids
Journal of Molecular Liquids, 5, 23.81%
Journal of Molecular Liquids
5 publications, 23.81%
Journal of Fluorescence
Journal of Fluorescence, 3, 14.29%
Journal of Fluorescence
3 publications, 14.29%
Dyes and Pigments
Dyes and Pigments, 2, 9.52%
Dyes and Pigments
2 publications, 9.52%
Optical Materials
Optical Materials, 1, 4.76%
Optical Materials
1 publication, 4.76%
Inorganic Chemistry Communication
Inorganic Chemistry Communication, 1, 4.76%
Inorganic Chemistry Communication
1 publication, 4.76%
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B, 1, 4.76%
Russian Journal of Physical Chemistry B
1 publication, 4.76%
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry, 1, 4.76%
Russian Journal of Inorganic Chemistry
1 publication, 4.76%
Thermochimica Acta
Thermochimica Acta, 1, 4.76%
Thermochimica Acta
1 publication, 4.76%
Coordination Chemistry Reviews
Coordination Chemistry Reviews, 1, 4.76%
Coordination Chemistry Reviews
1 publication, 4.76%
Data in Brief
Data in Brief, 1, 4.76%
Data in Brief
1 publication, 4.76%
Chemistry - A European Journal
Chemistry - A European Journal, 1, 4.76%
Chemistry - A European Journal
1 publication, 4.76%
Journal of Physical Chemistry A
Journal of Physical Chemistry A, 1, 4.76%
Journal of Physical Chemistry A
1 publication, 4.76%
Chemical Society Reviews
Chemical Society Reviews, 1, 4.76%
Chemical Society Reviews
1 publication, 4.76%
Physical Chemistry Chemical Physics
Physical Chemistry Chemical Physics, 1, 4.76%
Physical Chemistry Chemical Physics
1 publication, 4.76%
1
2
3
4
5

Citations by publishers

2
4
6
8
10
12
Elsevier
Elsevier, 12, 57.14%
Elsevier
12 publications, 57.14%
Springer Nature
Springer Nature, 3, 14.29%
Springer Nature
3 publications, 14.29%
Pleiades Publishing
Pleiades Publishing, 2, 9.52%
Pleiades Publishing
2 publications, 9.52%
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC), 2, 9.52%
Royal Society of Chemistry (RSC)
2 publications, 9.52%
Wiley
Wiley, 1, 4.76%
Wiley
1 publication, 4.76%
American Chemical Society (ACS)
American Chemical Society (ACS), 1, 4.76%
American Chemical Society (ACS)
1 publication, 4.76%
2
4
6
8
10
12
  • We do not take into account publications that without a DOI.
  • Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
  • Statistics recalculated weekly.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Antina E. V. et al. Synthesis, spectral-luminescent properties of B(III) and Zn(II) complexes with alkyl- and aryl-substituted dipyrrins and azadipyrrins // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 10. pp. 1187-1194.
GOST all authors (up to 50) Copy
Antina E. V., Berezin M. B., Dudina N. A., Burkova S. L., Nikonova A. Yu. Synthesis, spectral-luminescent properties of B(III) and Zn(II) complexes with alkyl- and aryl-substituted dipyrrins and azadipyrrins // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 10. pp. 1187-1194.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S0036023614100027
UR - https://doi.org/10.1134%2FS0036023614100027
TI - Synthesis, spectral-luminescent properties of B(III) and Zn(II) complexes with alkyl- and aryl-substituted dipyrrins and azadipyrrins
T2 - Russian Journal of Inorganic Chemistry
AU - Antina, E V
AU - Berezin, M B
AU - Dudina, N A
AU - Burkova, S L
AU - Nikonova, A Yu
PY - 2014
DA - 2014/09/25 00:00:00
PB - Pleiades Publishing
SP - 1187-1194
IS - 10
VL - 59
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
Cite this
BibTex Copy
@article{2014_Antina,
author = {E V Antina and M B Berezin and N A Dudina and S L Burkova and A Yu Nikonova},
title = {Synthesis, spectral-luminescent properties of B(III) and Zn(II) complexes with alkyl- and aryl-substituted dipyrrins and azadipyrrins},
journal = {Russian Journal of Inorganic Chemistry},
year = {2014},
volume = {59},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS0036023614100027},
number = {10},
pages = {1187--1194},
doi = {10.1134/S0036023614100027}
}
MLA
Cite this
MLA Copy
Antina, E. V., et al. “Synthesis, spectral-luminescent properties of B(III) and Zn(II) complexes with alkyl- and aryl-substituted dipyrrins and azadipyrrins.” Russian Journal of Inorganic Chemistry, vol. 59, no. 10, Sep. 2014, pp. 1187-1194. https://doi.org/10.1134%2FS0036023614100027.
Found error?