Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2 [Ge(HCit)2 ] · 4H2 O
Publication type: Journal Article
Publication date: 2015-01-06
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Onium bis(citrate)germanates (HNad)2[Ge(HCit)2] · 4H2O (I), (HIm)2[Ge(HCit)2] · 2H2O (II), and (HInd)2[Ge(HCit)2] · 2H2O (III) (where Nad is nicotinamide, Im is imidazole, and Ind is isoniazid) were synthesized by the reaction between bis(citrate)hydroxogermanic(IV) acid (H5O2)[Ge(OH)(H2Cit)(H2.5Cit)]2 · 2CH3COOH · 2H2O (H4Cit is citric acid) and organic bases. The complexes were characterized by elemental analysis, thermogravimetry, and IR spectroscopy. The X-ray diffraction analysis of complex I was performed. The structural units of a crystal of complex I were found to be centrosymmetric complex [Ge(HCit)2]2− anions, HNad+ cations, and crystallization water molecules.
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Seifullina I. I. et al. Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] · 4H2O // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 1. pp. 33-37.
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Seifullina I. I., Ilyukhin A. B., Martsinko E. É., Sergienko V. S., Chebanenko E. A. Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] · 4H2O // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 1. pp. 33-37.
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TY - JOUR
DO - 10.1134/S0036023615010143
UR - http://link.springer.com/10.1134/S0036023615010143
TI - Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] · 4H2O
T2 - Russian Journal of Inorganic Chemistry
AU - Seifullina, I I
AU - Ilyukhin, A. B.
AU - Martsinko, E É
AU - Sergienko, V S
AU - Chebanenko, E A
PY - 2015
DA - 2015/01/06
PB - Pleiades Publishing
SP - 33-37
IS - 1
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2015_Seifullina,
author = {I I Seifullina and A. B. Ilyukhin and E É Martsinko and V S Sergienko and E A Chebanenko},
title = {Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] · 4H2O},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S0036023615010143},
number = {1},
pages = {33--37},
doi = {10.1134/S0036023615010143}
}
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MLA
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Seifullina, I. I., et al. “Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] · 4H2O.” Russian Journal of Inorganic Chemistry, vol. 60, no. 1, Jan. 2015, pp. 33-37. http://link.springer.com/10.1134/S0036023615010143.