Structural features of monomeric octahedral d 2 rhenium(V) oxo complexes with oxygen atoms in trans-positions to oxo ligands: Complexes with propoxo ligands in trans-positions to O(oxo)
Publication type: Journal Article
Publication date: 2015-03-24
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Some structural features of mononuclear octahedral rhenium(V) oxo complexes with oxygen atoms of propoxo ligands O(Pr-iso)− in trans-positions to multiply bonded oxo ligands are considered. The complexes contain monodentate inorganic or organic ligands or bi- and tetradentate organic ligands in the equatorial plane. Re-O(OPr)trans bonds, as well as the other bonds with (ORalkoxo)trans alkoxo ligands (R = Me, Et), are considerably shortened, instead of being elongated, due to the structural manifestation of the trans-effect of multiply bonded oxo ligands. This is explained by that these Re-O(ORalkoxo) bonds also have an increased multiplicity; that is, d2 rhenium(V) monooxomonoalkoxo complexes should be considered as pseudo-dioxo Re(=O)(=ORalkoxo) compounds.
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Sergienko V. S. Structural features of monomeric octahedral d 2 rhenium(V) oxo complexes with oxygen atoms in trans-positions to oxo ligands: Complexes with propoxo ligands in trans-positions to O(oxo) // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 3. pp. 285-291.
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Sergienko V. S. Structural features of monomeric octahedral d 2 rhenium(V) oxo complexes with oxygen atoms in trans-positions to oxo ligands: Complexes with propoxo ligands in trans-positions to O(oxo) // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 3. pp. 285-291.
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TY - JOUR
DO - 10.1134/S003602361503016X
UR - https://doi.org/10.1134/S003602361503016X
TI - Structural features of monomeric octahedral d 2 rhenium(V) oxo complexes with oxygen atoms in trans-positions to oxo ligands: Complexes with propoxo ligands in trans-positions to O(oxo)
T2 - Russian Journal of Inorganic Chemistry
AU - Sergienko, V S
PY - 2015
DA - 2015/03/24
PB - Pleiades Publishing
SP - 285-291
IS - 3
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2015_Sergienko,
author = {V S Sergienko},
title = {Structural features of monomeric octahedral d 2 rhenium(V) oxo complexes with oxygen atoms in trans-positions to oxo ligands: Complexes with propoxo ligands in trans-positions to O(oxo)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S003602361503016X},
number = {3},
pages = {285--291},
doi = {10.1134/S003602361503016X}
}
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Sergienko, V. S.. “Structural features of monomeric octahedral d 2 rhenium(V) oxo complexes with oxygen atoms in trans-positions to oxo ligands: Complexes with propoxo ligands in trans-positions to O(oxo).” Russian Journal of Inorganic Chemistry, vol. 60, no. 3, Mar. 2015, pp. 285-291. https://doi.org/10.1134/S003602361503016X.
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