Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion
V V Avdeeva
1
,
I N Polyakova
1
,
L. V. Goeva
1
,
E. A. Malinina
1
,
A P Zhdanov
1
,
K Yu Zhizhin
1
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2015-07-07
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Synthesis of cobalt(II) and nickel(II) complexes with the closo-decaborate anion and benzimidazole derivatives (L1 = C13N3H11, L2 = C15N3H13) of the general formula [ML3][B10H10] (M = Co, Ni) is described. Complexes have been characterized by elemental analysis, IR and UV spectroscopy. The structure of a [Ni(L1)3][B10H10] · 1.797CH3CN single crystal has been determined by X-ray diffraction. The imidazole and pyridine N atoms of three L1 molecules, two of which are disordered, form the distorted octahedral environment of the Ni atom. In the crystal, the majority of complexes [Ni(L1)3]2+ have the meridional configuration. The Ni-N bonds with the imidazole nitrogen atoms (2.010(4)–2.076(3) Å) are shorter than those with the pyridine atoms (2.132(4)–2.179(5) Å). This nonequivalence of the Ni-N bonds is responsible for the low magnetic susceptibility of the compound.
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Avdeeva V. V. et al. Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 817-822.
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Avdeeva V. V., Polyakova I. N., Goeva L. V., Malinina E. A., Zhdanov A. P., Zhizhin K. Yu., Kuznetsov N. T. Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 817-822.
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TY - JOUR
DO - 10.1134/S0036023615070037
UR - https://doi.org/10.1134/S0036023615070037
TI - Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion
T2 - Russian Journal of Inorganic Chemistry
AU - Avdeeva, V V
AU - Polyakova, I N
AU - Goeva, L. V.
AU - Malinina, E. A.
AU - Zhdanov, A P
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2015
DA - 2015/07/07
PB - Pleiades Publishing
SP - 817-822
IS - 7
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2015_Avdeeva,
author = {V V Avdeeva and I N Polyakova and L. V. Goeva and E. A. Malinina and A P Zhdanov and K Yu Zhizhin and N. T. Kuznetsov},
title = {Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0036023615070037},
number = {7},
pages = {817--822},
doi = {10.1134/S0036023615070037}
}
Cite this
MLA
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Avdeeva, V. V., et al. “Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion.” Russian Journal of Inorganic Chemistry, vol. 60, no. 7, Jul. 2015, pp. 817-822. https://doi.org/10.1134/S0036023615070037.
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