Reactions of the [B10H10]2− anion with nucleophiles in the presence of halides of group IIIA and IVB elements
E Yu Matveev
1, 2
,
A. S. Kubasov
1
,
G A Razgonyaeva
1
,
I N Polyakova
1
,
K Yu Zhizhin
1, 2
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2015-07-07
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The study deals with reactions of the closo-decaborate anion [B10H10]2− with a number of nucleophiles (cyclic ethers and thioethers, N,N-substituted amides, and nitriles) in the presence of Lewis acids, halides of Group IIIA and IVB elements (BF3 · Et2O, AlCl3, TiBr4, TiI4, ZrCl4, ZrI4, and HfCl4), which act as electrophilic inductors of the nucleophilic substitution. This group of reactions allows the preparation of closo-decaborate derivatives with one or two exopolyhedral substituents. The method is distinguished by high yields (more than 80%) and high regioselectivity of substitution and can also be used to prepare disubstituted closo-decaborate derivatives.
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Total citations:
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Citations from 2024:
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(8%)
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GOST
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Matveev E. Yu. et al. Reactions of the [B10H10]2− anion with nucleophiles in the presence of halides of group IIIA and IVB elements // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 776-785.
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Matveev E. Yu., Kubasov A. S., Razgonyaeva G. A., Polyakova I. N., Zhizhin K. Yu., Kuznetsov N. T. Reactions of the [B10H10]2− anion with nucleophiles in the presence of halides of group IIIA and IVB elements // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 776-785.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023615070104
UR - https://doi.org/10.1134/S0036023615070104
TI - Reactions of the [B10H10]2− anion with nucleophiles in the presence of halides of group IIIA and IVB elements
T2 - Russian Journal of Inorganic Chemistry
AU - Matveev, E Yu
AU - Kubasov, A. S.
AU - Razgonyaeva, G A
AU - Polyakova, I N
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2015
DA - 2015/07/07
PB - Pleiades Publishing
SP - 776-785
IS - 7
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Matveev,
author = {E Yu Matveev and A. S. Kubasov and G A Razgonyaeva and I N Polyakova and K Yu Zhizhin and N. T. Kuznetsov},
title = {Reactions of the [B10H10]2− anion with nucleophiles in the presence of halides of group IIIA and IVB elements},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0036023615070104},
number = {7},
pages = {776--785},
doi = {10.1134/S0036023615070104}
}
Cite this
MLA
Copy
Matveev, E. Yu., et al. “Reactions of the [B10H10]2− anion with nucleophiles in the presence of halides of group IIIA and IVB elements.” Russian Journal of Inorganic Chemistry, vol. 60, no. 7, Jul. 2015, pp. 776-785. https://doi.org/10.1134/S0036023615070104.