Structure of N-substituted copper(II) hydroxamates in crystalline state and frozen solution
Publication type: Journal Article
Publication date: 2015-07-07
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Two CuL2 complexes, where L = R1N(O)-(O)CR2, R1 = tert-Bu, R2 = Me (I) and R1 = Me, and R2 = tert-Bu (II) have been structurally studied by X-ray diffraction. According to electron paramagnetic resonance (EPR) data, the complexes exist in dichloromethane at 77 K as two mononuclear isomeric species. The species whose spectrum is described by a spin Hamiltonian with a high hyperfine structure (HFS) constant is a cis-isomer. The species with a smaller HFS constant is classified as a trans-isomer. The trans-isomer of compound II forms an associate with dichloromethane molecules.
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Rotov A. V. et al. Structure of N-substituted copper(II) hydroxamates in crystalline state and frozen solution // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 866-870.
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Rotov A. V., Ugolkova E. A., Lermontova E. Kh., Beirakhov A. G. Structure of N-substituted copper(II) hydroxamates in crystalline state and frozen solution // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 866-870.
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TY - JOUR
DO - 10.1134/S0036023615070128
UR - http://link.springer.com/10.1134/S0036023615070128
TI - Structure of N-substituted copper(II) hydroxamates in crystalline state and frozen solution
T2 - Russian Journal of Inorganic Chemistry
AU - Rotov, A V
AU - Ugolkova, E. A.
AU - Lermontova, E Kh
AU - Beirakhov, A G
PY - 2015
DA - 2015/07/07
PB - Pleiades Publishing
SP - 866-870
IS - 7
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2015_Rotov,
author = {A V Rotov and E. A. Ugolkova and E Kh Lermontova and A G Beirakhov},
title = {Structure of N-substituted copper(II) hydroxamates in crystalline state and frozen solution},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S0036023615070128},
number = {7},
pages = {866--870},
doi = {10.1134/S0036023615070128}
}
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MLA
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Rotov, A. V., et al. “Structure of N-substituted copper(II) hydroxamates in crystalline state and frozen solution.” Russian Journal of Inorganic Chemistry, vol. 60, no. 7, Jul. 2015, pp. 866-870. http://link.springer.com/10.1134/S0036023615070128.
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