Synthesis and magnetic properties of iron(II) closo-borate complexes with tris(3,5-dimethylpyrazol-1-yl)methane
Publication type: Journal Article
Publication date: 2015-07-07
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Methods are developed for preparing iron(II) complexes with tris(3,5-dimethylpyrazol-1-yl)methane {HC(3,5-dmpz)3} and closo-borate(2-) ions, namely [Fe{HC(3,5-dmpz)3}2]B10H10 · H2O (I) and [Fe{HC(3,5-dmpz)3}2]B12H12 · H2O (II). These complexes were characterized by static magnetic susceptibility measurements (2–325 K), electronic spectroscopy (diffuse reflectance spectra), and IR spectroscopy. The complexes have a distorted octahedral geometry of the coordination polyhedron; the coordination core is FeN6. μeff(T) studies show low-temperature incomplete spin crossover in complex I and antiferromagnetic exchange coupling among iron(II) unpaired electrons at temperatures below 90 K in complex II. Complex I shows thermochromism; the color transition upon cooling is white ↔ pink.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
|
|
|
Russian Journal of Inorganic Chemistry
13 publications, 56.52%
|
|
|
Polyhedron
3 publications, 13.04%
|
|
|
Журнал неорганической химии
2 publications, 8.7%
|
|
|
Mendeleev Communications
1 publication, 4.35%
|
|
|
Crystals
1 publication, 4.35%
|
|
|
Russian Chemical Bulletin
1 publication, 4.35%
|
|
|
Journal of Molecular Structure
1 publication, 4.35%
|
|
|
Dalton Transactions
1 publication, 4.35%
|
|
|
2
4
6
8
10
12
14
|
Publishers
|
2
4
6
8
10
12
14
|
|
|
Pleiades Publishing
13 publications, 56.52%
|
|
|
Elsevier
4 publications, 17.39%
|
|
|
The Russian Academy of Sciences
2 publications, 8.7%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 4.35%
|
|
|
MDPI
1 publication, 4.35%
|
|
|
Springer Nature
1 publication, 4.35%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 4.35%
|
|
|
2
4
6
8
10
12
14
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
23
Total citations:
23
Citations from 2024:
7
(30.44%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shakirova O. G. et al. Synthesis and magnetic properties of iron(II) closo-borate complexes with tris(3,5-dimethylpyrazol-1-yl)methane // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 786-789.
GOST all authors (up to 50)
Copy
Shakirova O. G., Lavrenova L. G., Bogomyakov A. S., Zhizhin K. Yu., Kuznetsov N. T. Synthesis and magnetic properties of iron(II) closo-borate complexes with tris(3,5-dimethylpyrazol-1-yl)methane // Russian Journal of Inorganic Chemistry. 2015. Vol. 60. No. 7. pp. 786-789.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S003602361507013X
UR - https://doi.org/10.1134/S003602361507013X
TI - Synthesis and magnetic properties of iron(II) closo-borate complexes with tris(3,5-dimethylpyrazol-1-yl)methane
T2 - Russian Journal of Inorganic Chemistry
AU - Shakirova, O G
AU - Lavrenova, L G
AU - Bogomyakov, A S
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2015
DA - 2015/07/07
PB - Pleiades Publishing
SP - 786-789
IS - 7
VL - 60
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Shakirova,
author = {O G Shakirova and L G Lavrenova and A S Bogomyakov and K Yu Zhizhin and N. T. Kuznetsov},
title = {Synthesis and magnetic properties of iron(II) closo-borate complexes with tris(3,5-dimethylpyrazol-1-yl)methane},
journal = {Russian Journal of Inorganic Chemistry},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S003602361507013X},
number = {7},
pages = {786--789},
doi = {10.1134/S003602361507013X}
}
Cite this
MLA
Copy
Shakirova, O. G., et al. “Synthesis and magnetic properties of iron(II) closo-borate complexes with tris(3,5-dimethylpyrazol-1-yl)methane.” Russian Journal of Inorganic Chemistry, vol. 60, no. 7, Jul. 2015, pp. 786-789. https://doi.org/10.1134/S003602361507013X.