Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5)
A P Zhdanov
1
,
A Yu Bykov
1
,
A. S. Kubasov
1
,
I N Polyakova
1
,
G A Razgonyaeva
1
,
K Yu Zhizhin
1
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2017-04-27
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Reaction of tetrabutylammonium salts of [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5) anions with water results in N-borylated iminols (Bu4N)[2-B10H9NH=C(OH)R], and in the presence of an alkali, corresponding N-substituted amides (Bu4N)2[2-B10H9NH-C(=O)R] are formed. The compounds obtained are identified by IR, ESI/MS, and 1H, 11B, and 13C NMR spectroscopy. The crystal structure of compound (Bu4N)[2-B10H9(Z-{NHC(OH)C2H5})] is studied by X-ray diffraction.
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Total citations:
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Citations from 2025:
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Zhdanov A. P. et al. Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5) // Russian Journal of Inorganic Chemistry. 2017. Vol. 62. No. 4. pp. 468-475.
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Zhdanov A. P., Bykov A. Yu., Kubasov A. S., Polyakova I. N., Razgonyaeva G. A., Zhizhin K. Yu., Kuznetsov N. T. Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5) // Russian Journal of Inorganic Chemistry. 2017. Vol. 62. No. 4. pp. 468-475.
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TY - JOUR
DO - 10.1134/S0036023617040210
UR - https://doi.org/10.1134/S0036023617040210
TI - Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5)
T2 - Russian Journal of Inorganic Chemistry
AU - Zhdanov, A P
AU - Bykov, A Yu
AU - Kubasov, A. S.
AU - Polyakova, I N
AU - Razgonyaeva, G A
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2017
DA - 2017/04/27
PB - Pleiades Publishing
SP - 468-475
IS - 4
VL - 62
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2017_Zhdanov,
author = {A P Zhdanov and A Yu Bykov and A. S. Kubasov and I N Polyakova and G A Razgonyaeva and K Yu Zhizhin and N. T. Kuznetsov},
title = {Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2017},
volume = {62},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S0036023617040210},
number = {4},
pages = {468--475},
doi = {10.1134/S0036023617040210}
}
Cite this
MLA
Copy
Zhdanov, A. P., et al. “Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5).” Russian Journal of Inorganic Chemistry, vol. 62, no. 4, Apr. 2017, pp. 468-475. https://doi.org/10.1134/S0036023617040210.