Nickel(II) tetraaqua bis(benzoate) tris(phenylacethydrazide) complex [Ni(HL1)3 ](L2)2 · 4H2 O: Synthesis and crystal and molecular structure
Publication type: Journal Article
Publication date: 2017-12-05
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The synthesis, IR and Raman spectroscopic study, and X-ray diffraction analysis of [Ni(HL1)3](L2)2 · 4H2O (I), where HL1 is phenylacetic acid hydrazide and L2 is the benzoate monoanion, have been performed. The structural units of a crystal of complex I are complex [Ni(HL1)3]2+ cations, (L2)– anions, and crystallization water molecules. The nickel atom is coordinated to the three oxygen atoms at octahedron apices and the three nitrogen atoms of three bidentate chelate (О, N) ligands HL1 in cis,trans-meredianal (fac) conformation. The structural units of a crystal of complex I are bonded by a branched network of О–Н···О and N–H···O hydrogen bonds.
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Koksharova T. V. et al. Nickel(II) tetraaqua bis(benzoate) tris(phenylacethydrazide) complex [Ni(HL1)3](L2)2 · 4H2O: Synthesis and crystal and molecular structure // Russian Journal of Inorganic Chemistry. 2017. Vol. 62. No. 12. pp. 1568-1575.
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Koksharova T. V., Sergienko V. S., Surazhskaya M. D., Mandzii T. V., Mikhailov Yu. N. Nickel(II) tetraaqua bis(benzoate) tris(phenylacethydrazide) complex [Ni(HL1)3](L2)2 · 4H2O: Synthesis and crystal and molecular structure // Russian Journal of Inorganic Chemistry. 2017. Vol. 62. No. 12. pp. 1568-1575.
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TY - JOUR
DO - 10.1134/S0036023617120105
UR - https://doi.org/10.1134/S0036023617120105
TI - Nickel(II) tetraaqua bis(benzoate) tris(phenylacethydrazide) complex [Ni(HL1)3](L2)2 · 4H2O: Synthesis and crystal and molecular structure
T2 - Russian Journal of Inorganic Chemistry
AU - Koksharova, T V
AU - Sergienko, V S
AU - Surazhskaya, M D
AU - Mandzii, T V
AU - Mikhailov, Yu N
PY - 2017
DA - 2017/12/05
PB - Pleiades Publishing
SP - 1568-1575
IS - 12
VL - 62
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2017_Koksharova,
author = {T V Koksharova and V S Sergienko and M D Surazhskaya and T V Mandzii and Yu N Mikhailov},
title = {Nickel(II) tetraaqua bis(benzoate) tris(phenylacethydrazide) complex [Ni(HL1)3](L2)2 · 4H2O: Synthesis and crystal and molecular structure},
journal = {Russian Journal of Inorganic Chemistry},
year = {2017},
volume = {62},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S0036023617120105},
number = {12},
pages = {1568--1575},
doi = {10.1134/S0036023617120105}
}
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MLA
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Koksharova, T. V., et al. “Nickel(II) tetraaqua bis(benzoate) tris(phenylacethydrazide) complex [Ni(HL1)3](L2)2 · 4H2O: Synthesis and crystal and molecular structure.” Russian Journal of Inorganic Chemistry, vol. 62, no. 12, Dec. 2017, pp. 1568-1575. https://doi.org/10.1134/S0036023617120105.
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