Russian Journal of Inorganic Chemistry, volume 63, issue 4, pages 492-502
MALDI-TOF mass spectrometry of nanosized MoO2 . Structure and relative stability of isomers of lower molybdenum oxide cations
Publication type: Journal Article
Publication date: 2018-04-23
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
MALDI-TOF was used to study molybdenum dioxide (MoO2) containing a nanosized fraction. The composition of cationic clusters of nonstoichiometric lower molybdenum oxides in the gas phase was determined, and the thermodynamic stabilities and configurations of isomers were calculated for selected symmetric molecular structures and for cations MoSO8+and Mo5O9+. Molecular orbital analysis was performed for two trigonal-bipyramidal clusters Mo5O8 and Mo5O9. Changes in molybdenum–molybdenum interatomic distances in going from MoO8+ and Mo5O9+ cations to neutral clusters are discussed.
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International Journal of Mass Spectrometry
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International Journal of Mass Spectrometry
2 publications, 100%
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Elsevier
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Elsevier
2 publications, 100%
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Il`in E. G. et al. MALDI-TOF mass spectrometry of nanosized MoO2. Structure and relative stability of isomers of lower molybdenum oxide cations // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 4. pp. 492-502.
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Il`in E. G., Beirakhov A. G., Yarzhemsky V. G., Gekhman A. E., Buryak A. MALDI-TOF mass spectrometry of nanosized MoO2. Structure and relative stability of isomers of lower molybdenum oxide cations // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 4. pp. 492-502.
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TY - JOUR
DO - 10.1134/S0036023618040113
UR - https://doi.org/10.1134%2FS0036023618040113
TI - MALDI-TOF mass spectrometry of nanosized MoO2. Structure and relative stability of isomers of lower molybdenum oxide cations
T2 - Russian Journal of Inorganic Chemistry
AU - Il`in, E. G.
AU - Beirakhov, A G
AU - Yarzhemsky, V. G.
AU - Gekhman, A E
AU - Buryak, A.K
PY - 2018
DA - 2018/04/23 00:00:00
PB - Pleiades Publishing
SP - 492-502
IS - 4
VL - 63
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2018_Il`in,
author = {E. G. Il`in and A G Beirakhov and V. G. Yarzhemsky and A E Gekhman and A.K Buryak},
title = {MALDI-TOF mass spectrometry of nanosized MoO2. Structure and relative stability of isomers of lower molybdenum oxide cations},
journal = {Russian Journal of Inorganic Chemistry},
year = {2018},
volume = {63},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134%2FS0036023618040113},
number = {4},
pages = {492--502},
doi = {10.1134/S0036023618040113}
}
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Il`in, E. G., et al. “MALDI-TOF mass spectrometry of nanosized MoO2. Structure and relative stability of isomers of lower molybdenum oxide cations.” Russian Journal of Inorganic Chemistry, vol. 63, no. 4, Apr. 2018, pp. 492-502. https://doi.org/10.1134%2FS0036023618040113.
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