Russian Journal of Inorganic Chemistry, volume 63, issue 10, pages 1326-1332
Effect of Alkyl, Aryl, and meso-Aza Substitution on the Thermal Stability of BODIPY
Publication type: Journal Article
Publication date: 2018-10-16
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The effect of peripheral alkyl, aryl, and meso-aza substitution on the thermal stability of BODIPYs in an argon or oxygen atmosphere has been analyzed using thermogravimetric study results. It has been shown that an increase in the length of 2,6-alkyl substituents to seven carbon atoms is accompanied by the growth of BODIPY thermal stability by 80°C. The greatest increase in the destruction temperature of BODIPY (by 100°C) is attained via the introduction of phenyl groups in the 1,3,5,7-positions of its dipyrromethenmethene framework. meso-Aza substitution does not almost produce any effect on the thermal stability of BODIPY dyes. The BODIPY destruction beginning temperature decreases by 60–90°C in the presence of air oxygen. The thermal stability of BODIPY tends to decrease with reducing degree and symmetry of alkyl substitution in the dipyrromethene framework. A lower thermal stability of BODIPY in comparison with zinc(II) dipyrromethenates is due to the participation of fluorine atoms in intramolecular redox processes.
Citations by journals
|
1
|
|
|
Inorganic Chemistry Communication
|
Inorganic Chemistry Communication
1 publication, 12.5%
|
|
Dyes and Pigments
|
Dyes and Pigments
1 publication, 12.5%
|
|
ChemistrySelect
|
ChemistrySelect
1 publication, 12.5%
|
|
Designs
|
Designs
1 publication, 12.5%
|
|
Photochemistry and Photobiology
|
Photochemistry and Photobiology
1 publication, 12.5%
|
|
European Journal of Organic Chemistry
|
European Journal of Organic Chemistry
1 publication, 12.5%
|
|
Russian Journal of Inorganic Chemistry
|
Russian Journal of Inorganic Chemistry
1 publication, 12.5%
|
|
1
|
Citations by publishers
|
1
2
3
|
|
|
Wiley
|
Wiley
3 publications, 37.5%
|
|
Elsevier
|
Elsevier
2 publications, 25%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 12.5%
|
|
Pleiades Publishing
|
Pleiades Publishing
1 publication, 12.5%
|
|
1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[2,2,3,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["25","25","37.5","12.5"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Inorganic Chemistry Communication","Dyes and Pigments","ChemistrySelect","Designs","Photochemistry and Photobiology","European Journal of Organic Chemistry","Russian Journal of Inorganic Chemistry"],"ids":[22802,10101,8021,28806,2408,19472,426],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[12.5,12.5,12.5,12.5,12.5,12.5,12.5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Elsevier","Multidisciplinary Digital Publishing Institute (MDPI)","Pleiades Publishing"],"ids":[11,17,202,101],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[3,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[37.5,25,12.5,12.5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bumagina N. A. et al. Effect of Alkyl, Aryl, and meso-Aza Substitution on the Thermal Stability of BODIPY // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 10. pp. 1326-1332.
GOST all authors (up to 50)
Copy
Bumagina N. A., Kritskaya A. Yu., Antina E. V., Berezin M. B., Vyugin A. I. Effect of Alkyl, Aryl, and meso-Aza Substitution on the Thermal Stability of BODIPY // Russian Journal of Inorganic Chemistry. 2018. Vol. 63. No. 10. pp. 1326-1332.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023618100030
UR - https://doi.org/10.1134%2FS0036023618100030
TI - Effect of Alkyl, Aryl, and meso-Aza Substitution on the Thermal Stability of BODIPY
T2 - Russian Journal of Inorganic Chemistry
AU - Bumagina, N A
AU - Kritskaya, A Yu
AU - Antina, E V
AU - Berezin, M B
AU - Vyugin, A I
PY - 2018
DA - 2018/10/16 00:00:00
PB - Pleiades Publishing
SP - 1326-1332
IS - 10
VL - 63
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex
Copy
@article{2018_Bumagina,
author = {N A Bumagina and A Yu Kritskaya and E V Antina and M B Berezin and A I Vyugin},
title = {Effect of Alkyl, Aryl, and meso-Aza Substitution on the Thermal Stability of BODIPY},
journal = {Russian Journal of Inorganic Chemistry},
year = {2018},
volume = {63},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134%2FS0036023618100030},
number = {10},
pages = {1326--1332},
doi = {10.1134/S0036023618100030}
}
Cite this
MLA
Copy
Bumagina, N. A., et al. “Effect of Alkyl, Aryl, and meso-Aza Substitution on the Thermal Stability of BODIPY.” Russian Journal of Inorganic Chemistry, vol. 63, no. 10, Oct. 2018, pp. 1326-1332. https://doi.org/10.1134%2FS0036023618100030.