Synthesis and Structure of New Pt(IV) Perfluorocarboxylate Complexes and Their Reactivity with Respect to Alkanes and Cycloalkanes
Тип публикации: Journal Article
Дата публикации: 2019-01-01
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
New Pt(IV) perfluorocarboxylate complexes of the composition [Pt(RFCOO)4]n and M2[Pt(RFCOO)6] (RF = CF3, C2F5; M = Li, Na, K, Rb, Cs, NMe4) have been synthesized and studied. These complexes are strong oxidizing agents capable of oxidizing alkanes in trifluoroacetic acid under mild conditions to form trifluoroacetic acid esters and acting as catalysts for the oxidative trifluoroacetoxylation of alkanes, cycloalkanes, and framework compounds. They can also be used as starting compounds for the synthesis of other perfluorocarboxylate complexes of platinum in various oxidation states. The structure of (NMe4)2[Pt(CF3COO)6] · 6CF3COOH has been determined by X-ray diffraction.
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Stolyarov I. P. et al. Synthesis and Structure of New Pt(IV) Perfluorocarboxylate Complexes and Their Reactivity with Respect to Alkanes and Cycloalkanes // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 1. pp. 49-55.
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Stolyarov I. P., Cherkashina N. V., Churakov A., Naumkin A. V., Kornev A. B., Chernyak A. V., Martynenko V. M. Synthesis and Structure of New Pt(IV) Perfluorocarboxylate Complexes and Their Reactivity with Respect to Alkanes and Cycloalkanes // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 1. pp. 49-55.
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TY - JOUR
DO - 10.1134/S0036023619010200
UR - http://link.springer.com/10.1134/S0036023619010200
TI - Synthesis and Structure of New Pt(IV) Perfluorocarboxylate Complexes and Their Reactivity with Respect to Alkanes and Cycloalkanes
T2 - Russian Journal of Inorganic Chemistry
AU - Stolyarov, I P
AU - Cherkashina, N V
AU - Churakov, A.V.
AU - Naumkin, A. V.
AU - Kornev, A B
AU - Chernyak, A V
AU - Martynenko, V M
PY - 2019
DA - 2019/01/01
PB - Pleiades Publishing
SP - 49-55
IS - 1
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2019_Stolyarov,
author = {I P Stolyarov and N V Cherkashina and A.V. Churakov and A. V. Naumkin and A B Kornev and A V Chernyak and V M Martynenko},
title = {Synthesis and Structure of New Pt(IV) Perfluorocarboxylate Complexes and Their Reactivity with Respect to Alkanes and Cycloalkanes},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S0036023619010200},
number = {1},
pages = {49--55},
doi = {10.1134/S0036023619010200}
}
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Stolyarov, I. P., et al. “Synthesis and Structure of New Pt(IV) Perfluorocarboxylate Complexes and Their Reactivity with Respect to Alkanes and Cycloalkanes.” Russian Journal of Inorganic Chemistry, vol. 64, no. 1, Jan. 2019, pp. 49-55. http://link.springer.com/10.1134/S0036023619010200.
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