Russian Journal of Inorganic Chemistry, volume 64, issue 2, pages 185-189
Thermal Stability and Products of Decomposition of Hydroxylaminate Uranyl Complexes
Publication type: Journal Article
Publication date: 2019-02-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The thermal behavior of hydroxylaminate uranyl complexes [UO2(NH2O)2(H2O)2] ‧ H2O, [UO2(NH2O)2], and [UO2(i-C3H7NHO)2(H2O)2] ‧ 2H2O has been studied. The complexes decompose at a low temperature (<200°C) resulting in nanoscale powders of uranium dioxide. The composition of solid decomposition products for each complex has been determined by powder X-ray diffraction. For the complex with isopropylhydroxylamine, the composition of the gaseous decomposition products has been determined. Schemes of redox reactions, which can take place during the thermal decomposition of the complexes, are proposed. It has been suggested that the redox reactions are dependent on the substituents at the nitrogen atom of the hydroxylaminate ligands.
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New Journal of Chemistry
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
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Beirakhov A. G. et al. Thermal Stability and Products of Decomposition of Hydroxylaminate Uranyl Complexes // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 2. pp. 185-189.
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Beirakhov A. G., Rotov A. V., Efimov N. N., Il`in E. G., Gekhman A. E. Thermal Stability and Products of Decomposition of Hydroxylaminate Uranyl Complexes // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 2. pp. 185-189.
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TY - JOUR
DO - 10.1134/S0036023619020025
UR - https://doi.org/10.1134%2FS0036023619020025
TI - Thermal Stability and Products of Decomposition of Hydroxylaminate Uranyl Complexes
T2 - Russian Journal of Inorganic Chemistry
AU - Beirakhov, A G
AU - Rotov, A V
AU - Il`in, E. G.
AU - Gekhman, A E
AU - Efimov, N. N.
PY - 2019
DA - 2019/02/01 00:00:00
PB - Pleiades Publishing
SP - 185-189
IS - 2
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2019_Beirakhov,
author = {A G Beirakhov and A V Rotov and E. G. Il`in and A E Gekhman and N. N. Efimov},
title = {Thermal Stability and Products of Decomposition of Hydroxylaminate Uranyl Complexes},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134%2FS0036023619020025},
number = {2},
pages = {185--189},
doi = {10.1134/S0036023619020025}
}
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Beirakhov, A. G., et al. “Thermal Stability and Products of Decomposition of Hydroxylaminate Uranyl Complexes.” Russian Journal of Inorganic Chemistry, vol. 64, no. 2, Feb. 2019, pp. 185-189. https://doi.org/10.1134%2FS0036023619020025.
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