Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]–
A P Zhdanov
1
,
A V Nelyubin
1
,
I N Klyukin
1
,
N A Selivanov
1
,
E O Bortnikov
1, 2
,
M S Grigoriev
3
,
K Yu Zhizhin
1
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2019-07-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The work is devoted to the study of the process of nucleophilic addition of secondary amines to a multiple bond of the nitrile derivative of the closo-decaborate anion (NBu4) [2-B10H9NCCH3]. The process results to the regioselective and stereoselective formation of disubstituted amidines. The process is carried out under mild conditions and allows functionalization of amines of various structure. The compounds obtained are characterized by multinuclear NMR spectroscopy, IR spectroscopy, elemental analysis. For the substances (NBu4)[2-B10H9(E-NH=C(N(CH2)5CH3)] and (NBu4)[2-B10H9(E-NH=C(N(C2H4)2O)] the structures were confirmed by X-ray diffraction.
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18
Total citations:
18
Citations from 2025:
1
(5.56%)
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GOST
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Zhdanov A. P. et al. Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]– // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 7. pp. 841-846.
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Zhdanov A. P., Nelyubin A. V., Klyukin I. N., Selivanov N. A., Bortnikov E. O., Grigoriev M. S., Zhizhin K. Yu., Kuznetsov N. T. Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]– // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 7. pp. 841-846.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023619070180
UR - https://doi.org/10.1134/S0036023619070180
TI - Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]–
T2 - Russian Journal of Inorganic Chemistry
AU - Zhdanov, A P
AU - Nelyubin, A V
AU - Klyukin, I N
AU - Selivanov, N A
AU - Bortnikov, E O
AU - Grigoriev, M S
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2019
DA - 2019/07/01
PB - Pleiades Publishing
SP - 841-846
IS - 7
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Zhdanov,
author = {A P Zhdanov and A V Nelyubin and I N Klyukin and N A Selivanov and E O Bortnikov and M S Grigoriev and K Yu Zhizhin and N. T. Kuznetsov},
title = {Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]–},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0036023619070180},
number = {7},
pages = {841--846},
doi = {10.1134/S0036023619070180}
}
Cite this
MLA
Copy
Zhdanov, A. P., et al. “Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]–.” Russian Journal of Inorganic Chemistry, vol. 64, no. 7, Jul. 2019, pp. 841-846. https://doi.org/10.1134/S0036023619070180.