Synthesis and Physicochemical Properties of C-Borylated Amides Based on the closo-Decaborate Anion
I N Klyukin
1, 2
,
N A Selivanov
2
,
A Yu Bykov
2
,
A P Zhdanov
2
,
K Yu Zhizhin
2
,
N. T. Kuznetsov
2
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Reactions between monocarbonylated [B10H9CO]–closo-decaborate anion and N-nucleophiles have been studied. It has been discovered that not only primary and secondary, but also tertiary amines can enter the addition reactions. The C–N bond in the synthesized borylated amide derivatives has been found to be extremely labile and to cleave in an acidic medium to form the initial [B10H9CO]– ion. In neutral aqueous solutions, borylated amides are hydrolyzed to form carboxylate derivatives with the general formula [B10H9COOH]2–. All the synthesized derivatives have been separated out and studied by IR and NMR (1H, 11B, 13C) spectroscopy.
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Klyukin I. N. et al. Synthesis and Physicochemical Properties of C-Borylated Amides Based on the closo-Decaborate Anion // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1405-1409.
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Klyukin I. N., Selivanov N. A., Bykov A. Yu., Zhdanov A. P., Zhizhin K. Yu., Kuznetsov N. T. Synthesis and Physicochemical Properties of C-Borylated Amides Based on the closo-Decaborate Anion // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1405-1409.
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TY - JOUR
DO - 10.1134/S0036023619110081
UR - https://doi.org/10.1134/S0036023619110081
TI - Synthesis and Physicochemical Properties of C-Borylated Amides Based on the closo-Decaborate Anion
T2 - Russian Journal of Inorganic Chemistry
AU - Klyukin, I N
AU - Selivanov, N A
AU - Bykov, A Yu
AU - Zhdanov, A P
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2019
DA - 2019/11/01
PB - Pleiades Publishing
SP - 1405-1409
IS - 11
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2019_Klyukin,
author = {I N Klyukin and N A Selivanov and A Yu Bykov and A P Zhdanov and K Yu Zhizhin and N. T. Kuznetsov},
title = {Synthesis and Physicochemical Properties of C-Borylated Amides Based on the closo-Decaborate Anion},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0036023619110081},
number = {11},
pages = {1405--1409},
doi = {10.1134/S0036023619110081}
}
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MLA
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Klyukin, I. N., et al. “Synthesis and Physicochemical Properties of C-Borylated Amides Based on the closo-Decaborate Anion.” Russian Journal of Inorganic Chemistry, vol. 64, no. 11, Nov. 2019, pp. 1405-1409. https://doi.org/10.1134/S0036023619110081.
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