Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Coordination compounds [Co(L1)3](Mal) · 4H2O (I) and [Ni(L2)3](Mal) · H2O (II) (L1 is benzohydrazide, L2 is phenylacethydrazide, and H2Mal is maleic acid) have been synthesized and characterized by IR spectroscopy and diffuse reflectance spectroscopy. Crystal structures of I and II have been determined by single-crystal X-ray diffraction. Structural units of crystals I and II are complex cations [Co(L1)3]2+ and [Ni(L2)3]2+, respectively, maleate-ions Mal2–, and crystallized water molecules bound by a branched system of hydrogen bonds. Metal atoms at the complex cations of crystals I and II have octahedral coordination (3O + 3N) formed by three bidentate chelate ligands Ln (n = 1, 2).
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Sergienko V. S. et al. Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1396-1404.
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Sergienko V. S., Koksharova T. V., Surazhskaya M. D., Mandzii T. V., Churakov A. Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1396-1404.
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TY - JOUR
DO - 10.1134/S0036023619110172
UR - http://link.springer.com/10.1134/S0036023619110172
TI - Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O
T2 - Russian Journal of Inorganic Chemistry
AU - Sergienko, V S
AU - Koksharova, T V
AU - Surazhskaya, M D
AU - Mandzii, T V
AU - Churakov, A.V.
PY - 2019
DA - 2019/11/01
PB - Pleiades Publishing
SP - 1396-1404
IS - 11
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2019_Sergienko,
author = {V S Sergienko and T V Koksharova and M D Surazhskaya and T V Mandzii and A.V. Churakov},
title = {Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S0036023619110172},
number = {11},
pages = {1396--1404},
doi = {10.1134/S0036023619110172}
}
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MLA
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Sergienko, V. S., et al. “Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O.” Russian Journal of Inorganic Chemistry, vol. 64, no. 11, Nov. 2019, pp. 1396-1404. http://link.springer.com/10.1134/S0036023619110172.