N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion
Тип публикации: Journal Article
Дата публикации: 2020-06-01
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Methods for the preparation of N-substituted hydroxylamine [B12H11NH2OH]– have been developed and optimized. The possibility of using two synthetic methods has been shown: (i) based on the hydroxylation of the deprotonated amino-closo-dodecaborate and (ii) the ipso-substitution of the iodonium substituent with free hydroxylamine. A theoretical study of the [B12H11NH2OH]– anion has been carried out by quantum-chemical calculations in the framework of density functional theory in order to determine its main structural characteristics.
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Nelyubin A. V. et al. N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion // Russian Journal of Inorganic Chemistry. 2020. Vol. 65. No. 6. pp. 795-799.
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Nelyubin A. V., Selivanov N. A., Bykov A. Yu., Klyukin I. N., Novikov A. S., Zhdanov A. P., Zhizhin K. Yu., Kuznetsov N. T. N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion // Russian Journal of Inorganic Chemistry. 2020. Vol. 65. No. 6. pp. 795-799.
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TY - JOUR
DO - 10.1134/S0036023620060133
UR - https://doi.org/10.1134/S0036023620060133
TI - N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion
T2 - Russian Journal of Inorganic Chemistry
AU - Nelyubin, A V
AU - Selivanov, N A
AU - Bykov, A Yu
AU - Klyukin, I N
AU - Novikov, A. S.
AU - Zhdanov, A P
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2020
DA - 2020/06/01
PB - Pleiades Publishing
SP - 795-799
IS - 6
VL - 65
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2020_Nelyubin,
author = {A V Nelyubin and N A Selivanov and A Yu Bykov and I N Klyukin and A. S. Novikov and A P Zhdanov and K Yu Zhizhin and N. T. Kuznetsov},
title = {N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion},
journal = {Russian Journal of Inorganic Chemistry},
year = {2020},
volume = {65},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S0036023620060133},
number = {6},
pages = {795--799},
doi = {10.1134/S0036023620060133}
}
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MLA
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Nelyubin, A. V., et al. “N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion.” Russian Journal of Inorganic Chemistry, vol. 65, no. 6, Jun. 2020, pp. 795-799. https://doi.org/10.1134/S0036023620060133.
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