Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion
Publication type: Journal Article
Publication date: 2020-10-30
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The interaction of the monocarbonyl derivative of the closo-decaborate anion [2-B10H9CO]– with O-nucleophiles has been considered. It has been found that primary, secondary, and tertiary alcohols can enter the addition reaction. It has been shown that the C–O bond is extremely labile in the obtained closo-borate derivatives of the general formula [2-B10H9COOR]2–, and upon heating, its cleavage occurs to form the starting [2-B10H9CO]–. In acidic aqueous solutions, hydrolysis of borylated esters occurs to form a carboxylate derivative of the general formula [2-B10H9COOH]2–. All the derivatives obtained have been isolated and characterized by IR as well as 1H, 11B, and 13C NMR spectroscopies.
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Klyukin I. N. et al. Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion // Russian Journal of Inorganic Chemistry. 2020. Vol. 65. No. 10. pp. 1547-1551.
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Klyukin I. N., Selivanov N. A., Bykov A. Yu., Zhdanov A. P., Zhizhin K. Yu., Kuznetsov N. T. Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion // Russian Journal of Inorganic Chemistry. 2020. Vol. 65. No. 10. pp. 1547-1551.
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TY - JOUR
DO - 10.1134/S0036023620100113
UR - https://doi.org/10.1134/S0036023620100113
TI - Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion
T2 - Russian Journal of Inorganic Chemistry
AU - Klyukin, I N
AU - Selivanov, N A
AU - Bykov, A Yu
AU - Zhdanov, A P
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2020
DA - 2020/10/30
PB - Pleiades Publishing
SP - 1547-1551
IS - 10
VL - 65
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2020_Klyukin,
author = {I N Klyukin and N A Selivanov and A Yu Bykov and A P Zhdanov and K Yu Zhizhin and N. T. Kuznetsov},
title = {Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion},
journal = {Russian Journal of Inorganic Chemistry},
year = {2020},
volume = {65},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S0036023620100113},
number = {10},
pages = {1547--1551},
doi = {10.1134/S0036023620100113}
}
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MLA
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Klyukin, I. N., et al. “Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion.” Russian Journal of Inorganic Chemistry, vol. 65, no. 10, Oct. 2020, pp. 1547-1551. https://doi.org/10.1134/S0036023620100113.
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