High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine
A D Ivanova
1
,
L G Lavrenova
1, 2
,
E V Korotaev
1
,
S.V Trubina
1
,
L A Sheludyakova
1
,
S. A. Petrov
3
,
K Yu Zhizhin
4
,
N. T. Kuznetsov
4
Publication type: Journal Article
Publication date: 2020-11-17
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
New iron(II) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L) and closo-borate(2–) anions—[FeL2][B10H10] ⋅ 2H2O and [FeL2][B12H12] ⋅ H2O—have been synthesized. The complexes have been characterized by static magnetic susceptibility measurements, electronic (diffuse reflectance spectra), IR, and EXAFS spectroscopy, and X-ray diffraction analysis. A study of the μeff(T) dependence in the temperature range 80–500 K has shown that the complexes exhibit a high-temperature spin crossover 1А1 ⇔ 5Т2.
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14
Total citations:
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Citations from 2024:
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(14%)
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GOST
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Ivanova A. D. et al. High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine // Russian Journal of Inorganic Chemistry. 2020. Vol. 65. No. 11. pp. 1687-1694.
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Ivanova A. D., Lavrenova L. G., Korotaev E. V., Trubina S., Sheludyakova L. A., Petrov S. A., Zhizhin K. Yu., Kuznetsov N. T. High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine // Russian Journal of Inorganic Chemistry. 2020. Vol. 65. No. 11. pp. 1687-1694.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023620110078
UR - https://doi.org/10.1134/S0036023620110078
TI - High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine
T2 - Russian Journal of Inorganic Chemistry
AU - Ivanova, A D
AU - Lavrenova, L G
AU - Korotaev, E V
AU - Trubina, S.V
AU - Sheludyakova, L A
AU - Petrov, S. A.
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2020
DA - 2020/11/17
PB - Pleiades Publishing
SP - 1687-1694
IS - 11
VL - 65
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Ivanova,
author = {A D Ivanova and L G Lavrenova and E V Korotaev and S.V Trubina and L A Sheludyakova and S. A. Petrov and K Yu Zhizhin and N. T. Kuznetsov},
title = {High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine},
journal = {Russian Journal of Inorganic Chemistry},
year = {2020},
volume = {65},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0036023620110078},
number = {11},
pages = {1687--1694},
doi = {10.1134/S0036023620110078}
}
Cite this
MLA
Copy
Ivanova, A. D., et al. “High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine.” Russian Journal of Inorganic Chemistry, vol. 65, no. 11, Nov. 2020, pp. 1687-1694. https://doi.org/10.1134/S0036023620110078.
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