Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3 ]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion)
V S Sergienko
1, 2
,
T V Koksharova
3
,
A.V. Churakov
1
,
T V Mandzii
3
,
M D Surazhskaya
1
,
O A Egorova
4
1
3
Mechnikov National University, Odessa, Ukraine
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Тип публикации: Journal Article
Дата публикации: 2021-10-01
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Coordination compounds of various nickel(II) carboxylates (valerate, benzoate, phthalate, maleate, fumarate) with salicyl hydrazide have been synthesized and studied by IR spectroscopy. The crystal structure of the complex of nickel(II) phthalate with salicyl hydrazide [NiL3]Pht (L is salicyl hydrazide, Pht2– is phthalic acid dianion) has been determined by X-ray diffraction. The structural units of the crystal are complex cations [NiL3]2+ and phthalic acid anions Pht2– joined together by cation–anion N–H…O, O–H…O hydrogen bonds. The nickel atom has distorted octahedron coordination formed by three oxygen and three nitrogen atoms of the three bidentate-chelate ligands L (Ni–O 2.027–2.059, Ni–N 2.067–2.097 Å).
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Russian Journal of Inorganic Chemistry
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Pleiades Publishing
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Sergienko V. S. et al. Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 10. pp. 1492-1499.
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Sergienko V. S., Koksharova T. V., Churakov A., Mandzii T. V., Surazhskaya M. D., Egorova O. A. Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 10. pp. 1492-1499.
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TY - JOUR
DO - 10.1134/S0036023621100156
UR - https://link.springer.com/10.1134/S0036023621100156
TI - Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion)
T2 - Russian Journal of Inorganic Chemistry
AU - Sergienko, V S
AU - Koksharova, T V
AU - Churakov, A.V.
AU - Mandzii, T V
AU - Surazhskaya, M D
AU - Egorova, O A
PY - 2021
DA - 2021/10/01
PB - Pleiades Publishing
SP - 1492-1499
IS - 10
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Sergienko,
author = {V S Sergienko and T V Koksharova and A.V. Churakov and T V Mandzii and M D Surazhskaya and O A Egorova},
title = {Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://link.springer.com/10.1134/S0036023621100156},
number = {10},
pages = {1492--1499},
doi = {10.1134/S0036023621100156}
}
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Sergienko, V. S., et al. “Synthesis and Characterization of Coordination Compounds of Nickel(II) Carboxylates with Salicylhydrazide. Crystal Structure of [NiL3]Pht (L is Salicylhydrazide, Pht2– is Phthalic Acid Anion).” Russian Journal of Inorganic Chemistry, vol. 66, no. 10, Oct. 2021, pp. 1492-1499. https://link.springer.com/10.1134/S0036023621100156.