Pleiades Publishing
Russian Journal of Inorganic Chemistry
,  том 66 ,  издание 12 ,  страницы 1798-1801

Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]–

Тип публикации: Journal Article
Дата публикации: 2021-12-14
Pleiades Publishing
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ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Currently, the chemistry of carbonyl derivatives of the closo-borate anions is actively developing. It is of great interest to obtain protonated complexes of these types of clusters for further directed functionalization. The aim of this study is to develop an approach to the preparation of the protonated complex of the monocarbonyl derivative [B10H9CO⋅Hfac]0. In the course of the work, the target complex has been obtained by protonation of the [B10H9CO]– anion with an excess of trifluoromethanesulfonic acid CF3SO3OH. In this reaction, the boron cluster is quantitatively protonated. When a base is added, the protonation process becomes reversible.
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Russian Journal of Inorganic Chemistry
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Klyukin I. N. et al. Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]– // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 12. pp. 1798-1801.
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Klyukin I. N., Kolbunova A. V., Selivanov N. A., Bykov A. Yu., Zhdanov A. P., Zhizhin K. Yu., Kuznetsov N. T. Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]– // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 12. pp. 1798-1801.
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TY - JOUR
DO - 10.1134/S003602362112007X
UR - https://doi.org/10.1134/S003602362112007X
TI - Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]–
T2 - Russian Journal of Inorganic Chemistry
AU - Klyukin, I N
AU - Kolbunova, A V
AU - Selivanov, N A
AU - Bykov, A Yu
AU - Zhdanov, A P
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2021
DA - 2021/12/14
PB - Pleiades Publishing
SP - 1798-1801
IS - 12
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Klyukin,
author = {I N Klyukin and A V Kolbunova and N A Selivanov and A Yu Bykov and A P Zhdanov and K Yu Zhizhin and N. T. Kuznetsov},
title = {Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]–},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S003602362112007X},
number = {12},
pages = {1798--1801},
doi = {10.1134/S003602362112007X}
}
MLA
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Klyukin, I. N., et al. “Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]–.” Russian Journal of Inorganic Chemistry, vol. 66, no. 12, Dec. 2021, pp. 1798-1801. https://doi.org/10.1134/S003602362112007X.
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