Synthesis and Structures of Copper and Thallium(I) Coordination Compounds [Cu2[B10H10]]n and Tl2[B10H10] with the closo-Decaborate Anion
V V Avdeeva
1
,
A. S. Kubasov
1
,
S E Korolenko
1
,
L. V. Goeva
1
,
E. A. Malinina
1
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2022-05-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Solvent-free copper(I) and thallium(I) compounds of the general formula [M2[B10H10]] have been synthesized. The compounds have been identified by IR spectroscopy and X-ray diffraction. According to X-ray diffraction data, the structures of both compounds are three-dimensional frameworks. In copper(I) complex [Cu2[B10H10]]n, the formation of three-center M–H–B bonds is observed. In thallium(I) compound Tl2[B10H10], the bond between cations and anions is ionic, which is confirmed by IR spectroscopy data. The Hirschfeld surface analysis of the boron cluster anion was performed for both compounds to identify and analyze intramolecular interactions.
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Total citations:
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Citations from 2024:
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(19.05%)
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Avdeeva V. V. et al. Synthesis and Structures of Copper and Thallium(I) Coordination Compounds [Cu2[B10H10]]n and Tl2[B10H10] with the closo-Decaborate Anion // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 5. pp. 628-635.
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Avdeeva V. V., Kubasov A. S., Korolenko S. E., Goeva L. V., Malinina E. A., Kuznetsov N. T. Synthesis and Structures of Copper and Thallium(I) Coordination Compounds [Cu2[B10H10]]n and Tl2[B10H10] with the closo-Decaborate Anion // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 5. pp. 628-635.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S0036023622050023
UR - https://doi.org/10.1134/S0036023622050023
TI - Synthesis and Structures of Copper and Thallium(I) Coordination Compounds [Cu2[B10H10]]n and Tl2[B10H10] with the closo-Decaborate Anion
T2 - Russian Journal of Inorganic Chemistry
AU - Avdeeva, V V
AU - Kubasov, A. S.
AU - Korolenko, S E
AU - Goeva, L. V.
AU - Malinina, E. A.
AU - Kuznetsov, N. T.
PY - 2022
DA - 2022/05/01
PB - Pleiades Publishing
SP - 628-635
IS - 5
VL - 67
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2022_Avdeeva,
author = {V V Avdeeva and A. S. Kubasov and S E Korolenko and L. V. Goeva and E. A. Malinina and N. T. Kuznetsov},
title = {Synthesis and Structures of Copper and Thallium(I) Coordination Compounds [Cu2[B10H10]]n and Tl2[B10H10] with the closo-Decaborate Anion},
journal = {Russian Journal of Inorganic Chemistry},
year = {2022},
volume = {67},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S0036023622050023},
number = {5},
pages = {628--635},
doi = {10.1134/S0036023622050023}
}
Cite this
MLA
Copy
Avdeeva, V. V., et al. “Synthesis and Structures of Copper and Thallium(I) Coordination Compounds [Cu2[B10H10]]n and Tl2[B10H10] with the closo-Decaborate Anion.” Russian Journal of Inorganic Chemistry, vol. 67, no. 5, May. 2022, pp. 628-635. https://doi.org/10.1134/S0036023622050023.
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