Pleiades Publishing
Russian Journal of Inorganic Chemistry
,  volume 67 ,  issue 7 ,  pages 1018-1024

Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives

Publication type: Journal Article
Publication date: 2022-07-19
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
New hybrid 2,2'-bipyridinium halobismuthates ([bipyH]+) (I and II), 7,8-dihydro-6H-dipyrido[1,2-a:2',1'-c][1,4]diazepine-5,9-diium ([bipyC3]2+) (III), 6,7,8,9-tetrahydrodipyrido[1,2-a:2',1'-c][1,4]diazocin-5,10-diium ([bipyC4]2+) (IV), and 1,1'-(pentanediyl)bis(2,2'-bipyridinium) ((bipyH)2C5]4+) (V) have been isolated and characterized by X-ray diffraction. The structure of I contains a monoprotonated cation 2,2'-bipyridinium and the isolated [Bi2Br10]4– anion. 2,2'-Bipyridinium bromobismuthate II contains a polymeric anion and is isostructural to the previously described iodobismuthate. Bromobismuthate III includes [BiBr6]3– anions and water molecules. Iodobismuthate [bipyC3]2[Bi2I10] (VI) is isostructural to IV. The structure of V contains [(bipyH)2C5]4+ cations and three types of anions: [Bi2Br10]4–, [BiBr6]3–, and Br–. Compounds I, III, and VI have been isolated in pure form. The values of the optical band gap for them are 2.84, 2.88, and 2.11 eV, respectively.
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Balabanova S. P. et al. Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 7. pp. 1018-1024.
GOST all authors (up to 50) Copy
Balabanova S. P., Buikin P. A., Ilyukhin A. B., Rudenko A. Yu., Dorovatovskii P. V., Korlyukov A. A., Kotov V. Yu. Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 7. pp. 1018-1024.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036023622070038
UR - https://link.springer.com/10.1134/S0036023622070038
TI - Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives
T2 - Russian Journal of Inorganic Chemistry
AU - Balabanova, S P
AU - Buikin, P A
AU - Ilyukhin, A. B.
AU - Rudenko, A Yu
AU - Dorovatovskii, P. V.
AU - Korlyukov, A. A.
AU - Kotov, V Yu
PY - 2022
DA - 2022/07/19
PB - Pleiades Publishing
SP - 1018-1024
IS - 7
VL - 67
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Balabanova,
author = {S P Balabanova and P A Buikin and A. B. Ilyukhin and A Yu Rudenko and P. V. Dorovatovskii and A. A. Korlyukov and V Yu Kotov},
title = {Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives},
journal = {Russian Journal of Inorganic Chemistry},
year = {2022},
volume = {67},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://link.springer.com/10.1134/S0036023622070038},
number = {7},
pages = {1018--1024},
doi = {10.1134/S0036023622070038}
}
MLA
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MLA Copy
Balabanova, S. P., et al. “Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives.” Russian Journal of Inorganic Chemistry, vol. 67, no. 7, Jul. 2022, pp. 1018-1024. https://link.springer.com/10.1134/S0036023622070038.