Russian Journal of Inorganic Chemistry, volume 67, issue 7, pages 935-939

Synthesis and Crystal Structure of New Oxochloride (Mn,Mg)8Cl3O10

Publication type: Journal Article
Publication date: 2022-07-19
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ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
A method has been developed for synthesis of Mn8Cl3O10 oxochloride in an Ar flow (600°C, 8 h) from MnCl2 and MnO2. Some of the Mn2+ cations in this compound have been replaced by Mg2+ cations to fit the Mg0.6Mn7.4Cl3O10 formula. The composition of the oxochloride has been determined from the results of Rietveld refinement of its crystal structure using X-ray powder diffraction data and confirmed by X-ray electron probe analysis. It has been found that the Mg2+ cations in the structure preferentially occupy positions in a cubic array of oxygen atoms (MO8) rather than octahedral MCl6 sites.
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Dosaev K. A., Istomin S., ANTIPOV E. V. Synthesis and Crystal Structure of New Oxochloride (Mn,Mg)8Cl3O10 // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 7. pp. 935-939.
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Dosaev K. A., Istomin S., ANTIPOV E. V. Synthesis and Crystal Structure of New Oxochloride (Mn,Mg)8Cl3O10 // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 7. pp. 935-939.
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TY - JOUR
DO - 10.1134/S0036023622070063
UR - https://doi.org/10.1134%2FS0036023622070063
TI - Synthesis and Crystal Structure of New Oxochloride (Mn,Mg)8Cl3O10
T2 - Russian Journal of Inorganic Chemistry
AU - Istomin, S.Ya.
AU - ANTIPOV, E. V.
AU - Dosaev, K A
PY - 2022
DA - 2022/07/19 00:00:00
PB - Pleiades Publishing
SP - 935-939
IS - 7
VL - 67
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2022_Dosaev,
author = {S.Ya. Istomin and E. V. ANTIPOV and K A Dosaev},
title = {Synthesis and Crystal Structure of New Oxochloride (Mn,Mg)8Cl3O10},
journal = {Russian Journal of Inorganic Chemistry},
year = {2022},
volume = {67},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS0036023622070063},
number = {7},
pages = {935--939},
doi = {10.1134/S0036023622070063}
}
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Dosaev, K. A., et al. “Synthesis and Crystal Structure of New Oxochloride (Mn,Mg)8Cl3O10.” Russian Journal of Inorganic Chemistry, vol. 67, no. 7, Jul. 2022, pp. 935-939. https://doi.org/10.1134%2FS0036023622070063.
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