Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion
A. S. Kubasov
1
,
I. V. Novikov
2
,
P A Starodubets
3
,
V V Avdeeva
1
,
K Yu Zhizhin
1, 2
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2022-07-19
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The structures of cesium and tetraphenylphosphonium polyborates obtained in the course of mild oxidation of the closo-decaborate anion [B10H10]2– in water with a cerium(IV) salt to form Cs2[trans-B20H18] as the main product and in the course of long-term isomerization of the [trans-B20H18]2– anion under the action of UV irradiation to form (Ph4P)2[iso-B20H18] as the main product have been studied. The compounds have been isolated as solvates Cs[B5O6(OH)4]·2H2O and PPh4[B5O6(OH)4]·2DMF·H2O from the filtrates obtained after removing the target compounds from the reaction solutions. The formation of polyborates is explained by the processes of degradation of boron cluster anions in reaction solutions over time.
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Kubasov A. S. et al. Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 7. pp. 984-991.
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Kubasov A. S., Novikov I. V., Starodubets P. A., Avdeeva V. V., Zhizhin K. Yu., Kuznetsov N. T. Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion // Russian Journal of Inorganic Chemistry. 2022. Vol. 67. No. 7. pp. 984-991.
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RIS
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TY - JOUR
DO - 10.1134/S0036023622070130
UR - https://link.springer.com/10.1134/S0036023622070130
TI - Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion
T2 - Russian Journal of Inorganic Chemistry
AU - Kubasov, A. S.
AU - Novikov, I. V.
AU - Starodubets, P A
AU - Avdeeva, V V
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2022
DA - 2022/07/19
PB - Pleiades Publishing
SP - 984-991
IS - 7
VL - 67
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2022_Kubasov,
author = {A. S. Kubasov and I. V. Novikov and P A Starodubets and V V Avdeeva and K Yu Zhizhin and N. T. Kuznetsov},
title = {Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion},
journal = {Russian Journal of Inorganic Chemistry},
year = {2022},
volume = {67},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://link.springer.com/10.1134/S0036023622070130},
number = {7},
pages = {984--991},
doi = {10.1134/S0036023622070130}
}
Cite this
MLA
Copy
Kubasov, A. S., et al. “Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion.” Russian Journal of Inorganic Chemistry, vol. 67, no. 7, Jul. 2022, pp. 984-991. https://link.springer.com/10.1134/S0036023622070130.